Superconductivity in Breathing Kagome-Structured C14 Laves Phase XOs2(X = Zr, Hf)
Superconductor Science and Technology(2024)
摘要
Recently, the emergence of superconductivity in kagome metals has generated
significant interest due to its interaction with flat bands and topological
electronic states, which exhibit a range of unusual quantum characteristics.
This study thoroughly investigates largely unexplored breathing Kagome
structure C14 laves phase compounds XOs_2 (X = Zr, Hf) by XRD, electrical
transport, magnetization, and specific heat measurements. Our analyses confirm
the presence of the MgZn_2-type structure in ZrOs_2 and HfOs_2
compounds, exhibiting type-II superconductivity with critical temperature
(T_C) values of 2.90(3) K and 2.69(6) K, respectively. Furthermore,
specific heat measurements and an electron-phonon coupling constant suggest the
presence of weakly coupled BCS superconductivity in both compounds.
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