In-situ crosslinking of Tr?ger's base polymer onto a 3D Tr?ger's base-bridged porous network as gas separation membranes

Zhuoyi Huang,Junbo Yue,Shuzheng Sun,Feichao Wu,Jingde Li,Gang Li,Nanwen Li,Yanqin Yang

Separation and Purification Technology（2024）

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摘要

•3D-TB porous network and TB polymer were prepared under the same reaction system.•The in-situ crosslinking of TB to 3D-TB renders MMM with interfacial crosslinking.•The in-situ crosslinking enhances the mechanical properties of MMM.•The obtained MMM shows a significantly improved permeability and selectivity.

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关键词

Mixed-matrix membrane,Gas separation,Polymer of intrinsic microporosity,Tröger’s base,In-situ crosslinking

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