Direct Transformation of Nitriles to Cyanide Using Chloride Anion As Catalyst.
Chemical communications(2024)
摘要
A simple method is explored for the scission of C-CN bonds into aldehyde and CN- in air. The transformation was mediated by chloride anions. The cyanide anions were extracted from the reaction solution to form (Et4N)2[Zn(CN)4] and (Et4N)2[Ni(CN)4]. A chloride-induced reaction mechanism is proposed based on experimental studies and DFT calculations. This work might guide the study of halogen catalysts for C-C bond cleavage.
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