Crystal structure and Hirshfeld surface analysis of diethyl (3aS,3a1R,4S,5S,6R,6aS, 7R,9aS)-3a1,5,6,6a-tetrahydro-1H,3H,4H,7H-3a,6:7,9a-diepoxybenzo[de]isochromene-4,5-dicarboxyla te

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS(2024)

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摘要
In the title compound, C18H22O7, two hexane rings and an oxane ring are fused together. The two hexane rings tend toward a distorted boat conformation, while the tetrahydrofuran and dihydrofuran rings adopt envelope conformations. The oxane ring is puckered. The crystal structure features C-H center dot center dot center dot O hydrogen bonds, which link the molecules into a three-dimensional network. According to a Hirshfeld surface study, H center dot center dot center dot H (60.3%) and O center dot center dot center dot H/H center dot center dot center dot O (35.3%) interactions are the most significant contributors to the crystal packing.
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crystal structure,(1R,4S)-7-oxabicyclo[2.2.1]hept-2-ene,(1S,4S)-7-oxabicyclo[2.2.1]heptane,oxane,weak interactions,Hirshfeld surface analysis
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