Phoshporic acid actived biochar for efficient removal of paclobutrazol and alleviating its phytotoxicity to mung bean

Shuyi Zhong,Xu Zhang,Yufeng Chen, Kaiyuan Yu, Yuelin Huang,Lanzhi Li,Chunxia Ding,Jianwei Peng,Mei'e Zhong

CHEMICAL ENGINEERING SCIENCE(2024)

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摘要
Using biochar to absorb organic pollutants in water and soil is a simple and efficient method. However, most biochar is typically prepared at high temperatures (>500 degree celsius), resulting in low yield and high production costs and hence limiting its practical applications. This study aimed to prepare biochar (P-BC) through low-temperature (280 degree celsius) phosphoric acid assisted pyrolysis of cotton stalks. P-BC possessed a large specific surface area (389.96 m(2)g(-1)) and contained abundant oxygen functional groups as well as phosphorous and nitrogen nutrient elements. This study applied P-BC to remove paclobutrazol (PBZ) from water and remediate PBZ-polluted soil. The water adsorption capacity of P-BC was 192.89 mgg(-1). The adsorption mechanisms of P-BC included pore filling, hydrogen bonding, weak electrostatic effects, and pi-pi interactions. Adding 1 % P-BC to soil contaminated with 10 mgkg(-1) PBZ could alleviate PBZ induced phytotoxicity in mung bean seedlings, ensuring the normal growth of roots and plants.
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关键词
Biochar,Phosphoric acid activation,Paclobutrazol,Adsorption mechanism,Soil remediation
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