Heterobimetallic Dy³⁺ Complex [{2,6-Prⁱ₂C₆H₃NC(Me)= C(Me)NC₆H₃Prⁱ₂-2,6}2Dy][Li(THF)₄] Containing Ene-Diamide Ligands: Synthesis and Structure

~~A. O. Tolpygin, A. V. Cherkasov,A. A. Trifonov~~

~~RUSSIAN JOURNAL OF GENERAL CHEMISTRY（2023）~~

~~引用 0|浏览0~~

~~暂无评分~~

摘要

The reaction of DyCl3 with two equivalents of [Li(THF)(n)](2)[DAD(Me2)] [DAD(Me2) = 2,6-(Pr2C6H3NC)-C-i(Me) C(Me)NC6H3Pr2i-2,6] affords the ate-complex [Li(THF)(4)][Dy(DAD(Me2))(2)] in 71% yield. X-Ray analysis revealed that this complex presents a separated ion pair in which the Dy3+ ion is coordinated by two dianionic ene-diamide ligands.
更多
查看译文

~~关键词~~

~~rare earth metals,dysprosium,diazabutadiene ligand,dysprosium complexes~~

~~AI 理解论文~~

~~溯源树~~

样例

~~生成溯源树，研究论文发展脉络~~

~~Chat Paper~~

~~正在生成论文摘要~~

Heterobimetallic Dy3+ Complex [{2,6-Pri2C6H3NC(Me)= C(Me)NC6H3Pri2-2,6}2Dy][Li(THF)4] Containing Ene-Diamide Ligands: Synthesis and Structure

Heterobimetallic Dy³⁺ Complex [{2,6-Prⁱ₂C₆H₃NC(Me)= C(Me)NC₆H₃Prⁱ₂-2,6}2Dy][Li(THF)₄] Containing Ene-Diamide Ligands: Synthesis and Structure