Silver-Catalyzed Decarboxylative Remote Fluorination Via a Zwitterion-Promoted 1,4-Heteroaryl Migration
Organic letters(2024)
摘要
A silver-catalyzed decarboxylative remote fluorination via a zwitterion-promoted 1,4-heteroaryl migration has been developed. A variety of heteroaryl-tethered benzyl fluorides have been readily synthesized with good regioselectivity under mild conditions. The zwitterion of the substrate is suggested to accelerate the 1,4-heteroaryl migration, which determines the regioselectivity of this transformation.
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关键词
Enantioselective Fluorination
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