Tetracene cyclophanes showing controlled intramolecular singlet fission by through-space orientations

Hayato Sakai, Keigo Nonaka, Ryo Hayasaka, Shakkeeb Thazhathethil,Yoshimitsu Sagara,Taku Hasobe

CHEMICAL COMMUNICATIONS（2024）

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摘要

Tetracene cyclophanes: a series of cyclic tetracene dimers bridged by two flexible ethylene glycol units demonstrated enhanced intramolecular singlet fission through through-space orientations by suppressing the H-type excited complex. Tetracene cyclophanes: a series of cyclic tetracene dimers bridged by two flexible ethylene glycol units demonstrated enhanced intramolecular singlet fission through through-space orientations by suppressing the H-type excited complex.

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