Insight into the Nature of Carbon-Metal Bonding of N-Heterocyclic Carbenes in Gold/Silver Complexes and Nanoparticles Using DFT-Correlated Raman Spectroscopy: Strong Evidence for π-Backbonding

Lucille Kuster, Marilyne Bélanger-Bouliga,Thomas E. Shaw,Titel Jurca,Nazemi Ali,Mathieu Frenette

Nanoscale（2024）

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摘要

N-Heterocyclic carbenes (NHCs) have emerged as promising ligands for stabilizing metallic complexes, nanoclusters, nanoparticles (NPs) and surfaces. The carbon-metal bond between NHCs and metal atoms plays a crucial role in...

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