First detection in space of the high-energy isomer of cyanomethanimine: H2CNCN
The Astrophysical Journal(2024)
摘要
We report the first detection in the interstellar medium of
N-cyanomethanimine (H_2CNCN), the stable dimer of HCN of highest energy,
and the most complex organic molecule identified in space containing the
prebiotically relevant NCN backbone. We have identified a plethora of a-type
rotational transitions with 3 ≤ J_up≤ 11 and K_a≤
2 that belong to this species towards the Galactic Center G+0.693-0.027
molecular cloud, the only interstellar source showing the three
cyanomethanimine isomers (including the Z- and E- isomers of
C-cyanomethanimine, HNCHCN). We have derived a total column density for
H_2CNCN of (2.9±0.1)×10^12 cm^-2, which translates
into a total molecular abundance with respect to H_2 of (2.1±0.3)×10^-11. We have also revisited the previous detection of
E- and Z-HNCHCN, and found a total C/N-cyanomethanimine abundance ratio
of 31.8±1.8 and a Z/E-HNCHCN ratio of 4.5±0.2. While the
latter can be explained on the basis of thermodynamic equilibrium, chemical
kinetics are more likely responsible for the observed C/N-cyanomethanimine
abundance ratio, where the gas-phase reaction between methanimine (CH_2NH)
and the cyanogen radical (CN) arises as the primary formation route.
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关键词
Astrochemistry,Galactic center,Interstellar molecules,Interstellar clouds,Spectral line identification,Pre-biotic astrochemistry
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