Physicomechanical, Wettability, Corrosion, Thermal, and Microstructural Morphology Characteristics of Carbonized and Uncarbonized Bagasse Ash Waste-Reinforced Al-0.45Mg-0.35Fe-0.25Si-Based Composites: Fabrications and Characterizations.

ACS omega(2024)

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摘要
An effort was being made to incorporate waste bagasse ash (WBA) both in carbonized and uncarbonized form into the formulation of Al6063 matrix-based metal matrix composites (MMC's) by partially substituting ceramic particles for them. In the process of developing composites, comparative research on carbonized WBA and uncarbonized bagasse powder was carried out in the role of reinforcement. Microstructure investigations revealed that carbonized WBA particles were properly distributed throughout the aluminum-base metal matrix alloy. They also had the appropriate level of wettability. The reinforcement of carbonized WBA particles in AA6063-based matrix material had a maximum tensile strength of 110 MPa and a maximal hardness of 39 BHN when 3.75 wt % of the particles were used. The deterioration in tensile strength (6.25 wt % of WBA) and the appearance of porosity and blowholes can be enumerated by tensile fractography-based scanning electron microscopy (SEM) analysis. The reinforcement of carbonized WBA particles in AA6063-based matrix material was found to have a maximal percent elongation of 14.42% and the highest fracture toughness of 15 Joules when 1.25 wt % of the particles were employed. For AA6063/3.75 wt % carbonized WBA-based MMC's, the minimum percent porosity was determined to be 5.83, and the minimum thermal expansion was found to be 45 mm3. As the percentage of reinforcement in bagasse-reinforced composites increases, the density of the material, the amount of corrosion loss, and the cost all decrease gradually. The AA6063 matrix, with a composition of 3.75 wt % carbonized WBA-based MMC's, had satisfactory specific strength and corrosion loss. The AA6063 alloy composite's microstructure analysis revealed that carbonized WBA enhanced the material's mechanical characteristics, contributing to its excellent mechanical capabilities. The results of the corrosion test showed that carbonized WBA-reinforced composites exhibited reduced weight loss due to corrosion, whereas uncarbonized bagasse powder was an inappropriate reinforcement. The SEM analysis of AA6063 alloy/3.75 wt % carbonized WBA ash reinforcement-based MMC's exposed to a 3.5 wt % NaCl solution has exhibited the development of corrosion pits as a result of localized attack by the corrosive environment. The thermal expansion test showed that the composite with uncarbonized bagasse powder as reinforcement have a high shrinkage rate in comparison with the composite with 3.75 wt %. The composite's mechanical characteristics and thermal stability were enhanced by the presence of hard phases like SiO2, Al2O3, Fe2O3, CaO, and MgO, as revealed by X-ray diffraction analysis. This made it suitable for use in a variety of applications.
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