HALS-770 interlayer simultaneously block internal and external degradation paths of perovskite for stability and high efficiency perovskite solar cells
Chemical Engineering Journal(2024)
摘要
The stability of perovskite solar cells (PSCs) is a major problem limiting their application. Here, we proposed a feasible solution using bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate (HALS-770) as top protection layer of perovskite. HALS-770 interlayer can not only improve the antioxidant ability of perovskite by removing superoxide (O2·-) with help of hindered amine groups, but also suppress the internal and external degradation path of perovskite due to the co-existence of hydrophilic and hydrophobic groups. Moreover, it can block volatilization of organic cation and the migration of Ag+ and I-, thus improve thermal stability of perovskite and alleviate destruction of Ag electrode. In addition, the heterocycles N atom and carbonyl group in HALS-770 interact with the under-coordinated Pb2+, reducing the interface defects. As a result, the unencapsulated device maintains excellent stability over 95 % of its initial efficiency after 30 days in ambient condition with about 25–50 % humidity, and possesses remarkable continuous operation stability with projected T80 > 1400 h at maximum power point tracking in glove box, much higher than those of the pristine device. Meanwhile, HALS-770 enable the PCE of 21.88 % for PSC (0.06 cm2), which is among the highest efficiencies for MAPbI3 based PSCs with p-i-n structure, and the PCE of 19.07 % for PSM (4 cm2). And it is also suitable for FAMA-based devices with n-i-p structure, enabling an efficiency of 23.03 % (0.06 cm2) and excellent stability.
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关键词
Perovskite solar cell,External degradation,Internal degradation,Stability
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