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Switching from Gem-Difluorovinylation to Carboxylation: Ligand-enabled Palladium-Catalyzed Heck Annulation of Alkene-Tethered Aryl Halides with Sodium Difluorochloroacetate

Yu Xia, Wenqi Li, Minzhu Wei,Yonghong Zhang,Bin Wang,Shaofeng Wu,Chenjiang Liu

Organic chemistry frontiers（2024）

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Abstract
Reported herein is the use of ligand to tune palladium-catalyzed intramolecular Heck gem-difluorovinylation and carboxylation with alkene-tethered aryl halides, which provides an efficient avenue for building indolo[2,1-a]isoquinoline skeletons. The sodium...
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