Three important driving forces for creating qualitatively new phases in quantum materials are the topology of the materials' electronic band structures, frustration in the electrons' motion or magnetic interactions, and strong correlations between their charge, spin, and orbital degrees of freedom. In very few material systems do all of these aspects come together to contribute on an equal footing to stabilize new electronic states with unprecedented properties; however the search for such systems can be guided by models of configurational motifs or key sublattices that can host such physics. One of the most fascinating structural motifs for realizing this rich interplay of frustration, electronic topology, and electron correlation effects is the kagome lattice. In this review, we provide an overview of the theoretical underpinnings driving the physics of kagome lattices, and we then discuss experimental progress in realizing novel states enabled by kagome networks in crystalline materials. Different material classes are discussed with an emphasis on the phenomenologies of their electronic states and how they map to interactions arising from their kagome lattices.
In this work we provide a comprehensive review of theoretical and experimental studies of the properties of polarons formed by mobile impurities strongly interacting with quantum many-body systems. We present a unified perspective on the universal concepts and theoretical techniques used to characterize polarons in two distinct platforms, ultracold atomic gases and atomically-thin transition metal dichalcogenides, which are linked by many deep parallels. We review polarons in both fermionic and bosonic environments, highlighting their similarities and differences including the intricate interplay between few- and many-body physics. Various kinds of polarons with long-range interactions or in magnetic backgrounds are discussed, and the theoretical and experimental progress towards understanding interactions between polarons is described. We outline how polaron physics, regarded as the low density limit of quantum mixtures, provides fundamental insights regarding the phase diagram of complex condensed matter systems. Furthermore, we describe how polarons may serve as quantum sensors of many-body physics in complex environments. Our work highlights the open problems, identifies new research directions and provides a comprehensive framework for this rapidly evolving research field.
Complex systems are composed of many particles or agents that move and interact with one another. The underlying mathematical framework to model many of these systems must incorporate the spatial transport of particles and their interactions, as well as changes to their copy numbers, all of which can be formulated in terms of stochastic reaction-diffusion processes. The probabilistic representation of these processes is complex because of combinatorial aspects arising due to nonlinear interactions and varying particle numbers. This review presents the main field theory representations of stochastic reaction-diffusion systems, which handle these issues `under-the-hood'. First, we focus on bringing techniques familiar to theoretical physicists – such as second quantization, Fock space, and path integrals – back into the classical domain of reaction-diffusion systems. We demonstrate how various field theory representations can all be unified under a single basis-independent representation. We then extend existing quantum-based methods and notation to work directly on the level of the unifying representation, and we illustrate how they can be used to consistently obtain previous known results, such as numerical discretizations and relations between model parameters at multiple scales. Throughout the work, we contextualize how these representations mirror well-known models of chemical physics depending on their spatial resolution, as well as the corresponding macroscopic limits. The framework presented here may find applications in a diverse set of scientific fields, including physical chemistry, theoretical ecology, epidemiology, game theory and socio-economical models of complex systems. The presentation is done in a self-contained educational and unifying manner such that it can be followed by researchers across several fields.
Internal conversion is a vital vibronic loss mechanism which competes with all other photophysical mechanisms, and available in the literature is a plethora of information on the subject. However, this data is often difficult to penetrate due to its complexity. As well, due to the sheer number of methods, it is often difficult to understand which method is better for certain systems. This comprehensive review on the state of the art explores the history of internal conversion and provides context to its evolution up to modern quantum chemistry. We highlight the most prevalent methods used to study atomic systems, where they rise, and where they fall. Crucially, we note each methods and the corresponding results in a simplified manner, and thread everything together to elucidate how everything is related. This tapestry illustrating the up’s and down’s of internal conversion will aid researchers in their study of new and innovative materials, and provides a vital comparison of methods not easily gained.
The Cosmological Principle, which states that the Universe is homogeneous and isotropic (when averaged on large scales), is the foundational assumption of Friedmann-Lemaitre-Robertson-Walker (FLRW) cosmologies such as the current standard Lambda-Cold-Dark-Matter (ΛCDM) model. This simplification yields an exact solution to the Einstein field equations that relates space and time through a single time-dependent scale factor, which defines cosmological observables such as the Hubble parameter and the cosmological redshift. The validity of the Cosmological Principle, which underpins modern cosmology, can now be rigorously tested with the advent of large, nearly all-sky catalogs of radio galaxies and quasars. Surprisingly, the dipole anisotropy in the large-scale distribution of matter is found to be inconsistent with the expectation from kinematic aberration and Doppler boosting effects in a perturbed FLRW universe, which is the standard interpretation of the observed dipole in the cosmic microwave background (CMB). Although the matter dipole agrees in direction with that of the CMB dipole, it is anomalously larger, demonstrating that either the rest frames in which matter and radiation appear isotropic are not the same, or that there is an unexpected intrinsic anisotropy in at least one of them. This discrepancy now exceeds 5σ in significance. We review these recent findings, as well as the potential biases, systematic issues, and alternate interpretations that have been suggested to help alleviate the tension. We conclude that the cosmic dipole anomaly poses a serious challenge to FLRW cosmology, and the standard ΛCDM model in particular, as an adequate description of our Universe.
Quantum theory and general relativity are about one century old. At present, they are considered the best available explanations of physical reality, and they have been so far corroborated by all experiments realised so far. Nonetheless, the quest to unify them is still ongoing, with several yet untested proposals for a theory of quantum gravity. Here we review the nascent field of information-theoretic methods applied to designing tests of quantum gravity in the laboratory. This field emerges from the fruitful extension of quantum information theory methodologies beyond the domain of applicability of quantum theory itself, to cover gravity. We shall focus mainly on the detection of gravitational entanglement between two quantum probes, comparing this method with single-probe schemes. We shall review the experimental proposal that has originated this field, as well as its variants, their applications, and discuss their potential implications for the quantum theory of gravity. We shall also highlight the role of general information-theoretic principles in illuminating the search for quantum effects in gravity.
Competing magnetic interactions may stabilize smooth magnetization textures that can be characterized by a topological winding number. Such textures, which are spatially localized within a two-dimensional plane, are commonly known as skyrmions. On the classical level, their significance for fundamental science and their potential for applications, ranging from spintronic devices to unconventional computation platforms, have been intensively investigated in recent years. This Colloquium considers quantum effects associated with skyrmion textures: their theoretical origins, the experimental and material challenges associated with their detection, and the promise of exploiting them for quantum operations. Starting with classical skyrmions, we discuss their magnon and electron excitations and show how hybrid architectures offer new platforms for engineering quantum orders, including topological superconductivity. We then focus on the quantization of the skyrmion texture itself and formulate the long-time skyrmion dynamics in terms of collective coordinates. Next, we discuss the quantization of helicity and phenomena of macroscopic quantum tunneling: key concepts that fundamentally distinguish quantum skyrmions from their classical counterparts. Looking ahead, we propose material classes suitable for the realization of skyrmions in quantum spin systems and identify device architectures with the promise of achieving quantum operations. We close by addressing the advances in experimental methods which will be a prerequisite for resolving the quantum aspects of topological spin patterns, sensing their local dynamical response, and achieving their predicted functionalities in magnetic systems.
