Каталитическое Окисление Изопропилбензола Молекулярным Кислородом В Присутствии Тетрафенилпорфинов Металлов

Catalytic oxidation of cumene by molecular oxygen with tetraphenylporphins Co, Cu, Zn, In, Sn, Al has been studied. It was shown that tetraphenylporphines Co, Cu and Zn are very active catalysts as they catalyze decay of cumene hydro peroxide in addition to oxygen activation. Tetraphenylporphins In, Sn, Al are less active in this reaction as they do not catalyze hydro peroxide decay. It was found that catalytic activity of metal tetraphenylporphins changes slope oppositely to their potentials of electrochemical oxidation except tetraphenylporphin Cu.