In deep, ground-based imaging, about 15%-30% of object detections are expected to correspond to two or more true objects - these are called "unrecognized blends''. We use Machine Learning algorithms to detect unrecognized blends in deep ground-based photometry using only catalog-level information: colors, magnitude, and size. We compare the performance of Self Organizing Map, Random Forest, k-Nearest Neighbors, and Anomaly Detection algorithms. We test all algorithms on 9-band ($uBVri^{+}z^{++}YJH$) and 1-size (flux_radius in $\textit{i}$-band) measurements of the ground-based COSMOS catalog, and use COSMOS HST data as the truth for unrecognized blend. We find that 17% of objects in the ground-based COSMOS catalog are unrecognized blends. We show that some unrecognized blends can be identified as such using only catalog-level information; but not all blends can be easily identified. Nonetheless, our methods can be used to improve sample purity, and can identify approximately 30% to 80% of unrecognized blends while rejecting 10% to 50% of all detected galaxies (blended or unblended). The results are similar when only optical bands ($uBVri^{+}z^{++}$) and the size information is available. We also investigate the ability of these algorithms to remove photo-z outliers (identified with spectroscopic redshifts), and find that algorithms targeting color outliers perform better than algorithms targeting unrecognized blends. Our method can offer a cleaner galaxy sample with lower blending rates for future cosmological surveys such as the Legacy Survey of Space and Time (LSST), and can potentially improve the accuracy on cosmological parameter constraints at a moderate cost of precision.
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