Engineering Direct 3d–4f Orbital Coupling by Confining Cu–Ln Pairs in Paddlewheel Metal–organic Frameworks for Efficient CO 2 Electromethanation | AMiner
Engineering Direct 3d–4f Orbital Coupling by Confining Cu–Ln Pairs in Paddlewheel Metal–organic Frameworks for Efficient CO 2 Electromethanation
Direct 3d–4f orbital coupling engineered by confining Cu–Er pairs in paddlewheel frameworks strengthens *CO adsorption and lowers the *CO → *CHO barrier, enabling efficient CO 2 electromethanation with 82% CH 4 faradaic efficiency.
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