We experimentally demonstrated a high-performance multi-protocol continuous-variable quantum key distribution (CV-QKD) using one transceiver. The demonstrated multi-protocol CV-QKD system can simultaneously distribute 5 subcarriers with Gaussian, 4QAM, 16QAM, 64QAM, and 1024QAM modulation protocols based on orthogonal-frequency-division-multiplexing (OFDM) technology. Moreover, the modulation variance and probability distribution factor of 5 subcarriers are carefully optimized to maximize their respective SKRs. Besides, we innovatively design an effective OFDM-based DSP scheme and a precise dual-stage phase noise compensation scheme to realize a low excess noise for each subcarrier operating at a 2 GHz symbol rate. Thus, the multi-protocol CV-QKD achieves multiple SKRs of 48.79, 7.58, 23.67, 32.93, and 36.78 Mbps over a typical transmission distance of 50 km within a single transmission. Therefore, our work provides a practical solution to achieve highly efficient, interoperable, flexible, and secure QKDs for high-speed quantum secure communication.