PDRs4All XIX. the Evolution of the PAH Ionisation and PAH Size Distribution Across the Orion Bar

Context. JWST observations of the Orion Bar have revealed rich and diverse polycyclic aromatic hydrocarbon (PAH) emission. These observations allow for the first time a comprehensive characterisation of the charge state and size of the PAH population on morphologically resolved photodissociation regions (PDR) scales, properties closely linked to physical conditions of their inhabiting environments. Aims. We investigate the evolution of the PAH population's charge state and size across key physical zones in the Orion Bar, which include the H ii region, the atomic PDR (APDR), and three bright H I/H-2 dissociation fronts (DF1, DF2, and DF3). We connect changes in the PAH charge and size as probed by empirical emission proxies with the varying physical properties of their surrounding environments. Methods. Utilising the NASA Ames PAH Infrared Spectroscopic Database (PAHdb) and the pyPAHdb spectral modelling tool, we analysed the MIRI-MRS observations of the Orion Bar from the 'PDRs4All' JWST Early Release Science Program. Decomposition and modelling were performed on the 5-15 mu m spectrum across the entire JWST mosaic, as well as on the weighted average spectra of the five key physical zones. Results. pyPAHdb modelling reveals the fractional contribution of the different PAH charge states and sizes to the total PAH emission across the Orion Bar. Cationic PAH emission peaks in the APDR region, where neutral PAHs make a minimal contribution. Emission from neutral PAHs peaks in the H ii region that consists of emission from a face-on PDR associated with the background OMC-1 molecular cloud, and in the molecular cloud regions past DF2. The PAH anions are observed deep within the DF2 and DF3 zones. Small and medium-sized PAHs make up similar to 70% of the PAH emission across the mosaic, with the peak of the small PAH emission found between the DF2 and DF3 zones. The average PAH size in the Orion Bar ranges between similar to 60-74 N-C. The modelling reveals regions of top-down PAH formation at the ionisation front, and bottom-up PAH formation within the molecular cloud region. The PAH ionisation parameter, gamma, ranges between similar to 2-9 & times; 10(4). Intensity ratios that are empirical tracers of PAH ionisation (I-6.2/I-11.2, I-7.7/I-11.2, I-8.6/I-11.2) scale well with gamma in regions encompassing edge-on or face-on PDR emission, but their correlation weakens within the molecular cloud zone. Conclusions. Modelling of the 5-15 mu m PAH spectrum with pyPAHdb achieves a comprehensive characterisation of the net contribution of neutral and cationic PAHs across different environments, whereas empirical PAH proxy intensity ratio tracers can be highly variable and unreliable outside regions dominated by PDR emission. The derived average PAH size in the different physical zones is consistent with a view of PAHs being more extensively subjected to ultraviolet processing closer to the ionisation front, and less affected within the molecular cloud.