REACTION DYNAMICS IN CLUSTERS AND CONDENSED PHASES(1994)
Department of Chemistry
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摘要
The dynamics and structural properties of clusters composed of two chemical species are investigated. The demixing process starting from the unstable fully-mixed state in the clusters possesses some features that are similar to domain formation and growth following a critical quench in a binary fluid. The structural properties of the phase separated clusters differ from those of the bulk fluid and are studied as a function of the temperature, concentration and interaction strength.