Bulk metallic materials have ordinarily been produced by melting and solidification processes for the last several thousand years. However, metallic liquid is unstable at temperatures below the melting temperature and solidifies immediately into crystalline phases. Consequently, all bulk engineering alloys are composed of a crystalline structure. Recently, this common concept was exploded by the findings of the stabilization phenomenon of the supercooled liquid for a number of alloys in the Mg-, lanthanide-, Zr-, Ti-, Fe-, Co-, Pd–Cu- and Ni-based systems. The alloys with the stabilized supercooled liquid state have three features in their alloy components, i.e. multicomponent systems, significant atomic size ratios above 12%, and negative heats of mixing. The stabilization mechanism has also been investigated from experimental data of structure analyses and fundamental physical properties. The stabilization has enabled the production of bulk amorphous alloys in the thickness range of 1–100mm by using various casting processes. Bulk amorphous Zr-based alloys exhibit high mechanical strength, high fracture toughness and good corrosion resistance and have been used for sporting goods materials. The stabilization also leads to the appearance of a large supercooled liquid region before crystallization and enables high-strain rate superplasticity through Newtonian flow. The new Fe- and Co-based amorphous alloys exhibit a large supercooled liquid region and good soft magnetic properties which are characterized by low coercive force and high permeability. Furthermore, homogeneous dispersion of nanoscale particles into Zr-based bulk amorphous alloys was found to cause an improvement of tensile strength without detriment to good ductility. The discovery of the stabilization phenomenon, followed by the clarification of the stabilization criteria of the supercooled liquid, will promise the future definite development of bulk amorphous alloys as new basic science and engineering materials.
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