This paper focuses on the application of structuration theory, seeking to explicate analytical considerations by which key structurational constructs may be operationalized so as to guide a detailed empirical analysis. In so doing, the paper offers a methodological contribution in respect of the conduct of structurational-based IS research. Owing to its high level of abstraction, structuration theory raises difficulties at the level of empirical application and leaves the IS researcher with no obvious path to follow. Several key constructs have come from studies of the structurational modalities, but the issue of how these constructs may be operationalized remains obscure. An attempt is made here to overcome this deficiency by offering a number of elaborations of some of the central analytical dimensions, contributing to the creation of much needed clarity in terms of where and what to look for and which specifications to lay down at the operational level.