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    专

    台勾霉素衍生物在制备治疗寨卡病毒感染引起的相关疾病和/或症状的药物中的应用

    18859200643D0
    发明人
    黎孟枫, 张长生, 袁洁, 朱勋, 于暕辰, 张海波, 朱义广, 张光涛
    受让人
    中山大学, 中国科学院南海海洋研究所
    申请人
    ISEKI AGRICULT MACH
    申请号
    2014066605
    申请日
    2023-06-29
    公开(公告)号
    18859200643D0
    公开(公告)日
    1999-03-16
    IPC分类号
    A23G009/38A23G009/40A23G000/00A23G009/32A23G009/04
    CPC分类号
    -
    优先权号
    106413
    优先权日
    2003-03-20
    摘要

    Ultrasonic wave type electricity removing appts. comprises a reservoir water vessel comprising an insulating material, an appts. for generating ultrasonic waves by a piezoelectric ceramic oscillator dipped in the reservoir water, and AC/DC transformer with 100-240 V AC electric supply as a first side and a step up function for generating high AC or 4-10 KV and a step down function for generating low AC of 5-60 V as a second side, and a transistor oscillation circuit for emitting ultrasonic waves by the oscillator using DC converted from the low voltage AC by a bridge diode.

    USE/ADVANTAGE -Used for applying high voltage to water to ionise the water and atomise the ionised water, to remove static electricity. The appts. generates highly-charged mist by using a small electric power.

    权利要求
    1 . Method for producing a connection structure comprising a conductor via and a contact zone with a metal and semi-conductor compound in the extension of said conductor via, the connection structure extending between an upper semi-conductor layer receiving an active zone of at least one higher level transistor of a microelectronic device comprising several levels of semi-conductor layers arranged one above the other and at least one conducting zone located under the upper level, the method comprising: a) supplying a lower stage provided with at least one first electronic component arranged at least partially in a lower semi-conductor layer resting on a substrate, the electronic component being surmounted by at least one insulating layer and by said conducting zone, then, b) transferring onto the lower stage an upper semi-conductor layer, then c) producing at least partially said transistor of which the active zone extends in the upper semi-conductor layer and at least one metal region in contact with the active zone, d) carrying out at least one thermal annealing in such a way as to form from said metal region, said contact zone with a metal and semi-conductor compound base and in contact with said upper semi-conductor layer, said contact zone being located in the extension of a conductor via formed before and/or after the transferring, said conductor via extending under the upper semi-conductor layer and being arranged in contact with said conducting zone.
    2 . Method according to claim 1 , wherein the producing of the conductor via comprises, prior to the step b) of transferring: the formation through the insulating layer of a conducting element in contact with said conducting zone and said metal region in the extension of this conducting element, said metal region being flush on an upper face of the insulating layer, the transferring in the step b) being carried out in such a way that said metal region is put into contact with a lower face of the upper semi-conductor layer.
    3 . Method according to claim 2 , wherein the formation of the conducting element and of said metal region in its extension comprises steps of: forming the conducting element passing through the insulating layer, removing an upper portion of the conducting element, in such a way as to release a hole in the insulating layer, filling said hole with at least one metal material is such a way as to produce said metal region.
    4 . Method according to claim 1 , wherein the producing of the conductor via comprises, after the step b) of adding, steps of: forming of at least one opening passing through the upper semi-conductor layer, depositing of metal material in said opening in such a way as to form the metal region.
    5 . Method according to claim 4 , wherein the producing of the conductor via comprises, prior to the step b) of transferring: the formation through the insulating layer of a conducting element in contact with said conducting zone then with said metal region in the extension of this conducting element, and wherein the adding in the step b) is carried out in such a way that an insulating thickness is retained above an upper end of said conducting element, said opening passing through the upper semi-conductor layer being formed in such a way as to furthermore pass through said insulating thickness and to expose said upper end of said conducting element.
    6 . Method according to claim 5 , wherein at the step b) of transferring, the upper semi-conductor layer is coated with a first layer of dielectric material, and wherein said lower stage is coated with a second layer of dielectric material, the transferring being carried out by molecular bonding of the first layer of dielectric material on the second layer of dielectric material.
    7 . Method according to claim 4 , wherein the producing of the conductor via further comprises, after the production of said opening and the step d) of forming said contact zone with a metal and semi-conductor compound, the forming of a metal pad in said opening.
    8 . Method according to claim 4 , the producing of the conductor via comprises after the production of said opening, the production of a metal pad in this opening, said metal region being a region of said metal pad in contact with the upper semi-conductor layer.
    9 . Method according to claim 3 , wherein after the forming of said opening passing through the upper semi-conductor layer or of said hole in the insulating layer, a cleaning is carried out in said opening or in said hole prior to the depositing or the filling with metal material.
    10 . Method according to claim 1 , wherein prior to the step d), at least one metal zone is further formed on an upper face of the upper semi-conductor layer, the annealing carried out in the step d) being carried out in such a way as to form concomitantly with the forming of said contact zone with a metal and semi-conductor compound, a compound region of metal and semi-conductor in the extension of said metal zone.
    11 . Method according to claim 1 , wherein the source and drain regions of said transistor are doped in the step c), with the thermal annealing in the step d) being provided in such a way as to carry out an activation of doping agents of the source and drain regions.
    12 . Method according to claim 1 , wherein the thermal annealing carried out in the step d) is a laser annealing.
    13 . Method according to claim 1 , wherein said metal region is in contact with another active zone of another transistor, in such a way that said contact zone formed in the step d) with a metal and semi-conductor compound base is in contact with said other active zone.
    14 . Method according to claim 1 , wherein the semi-conductor layer is made of silicon and wherein the metal region has a cobalt and/or Ti and/or Ni base.
    15 . Method for producing a connection structure comprising a conductor via and a contact zone with a metal and semi-conductor compound in the extension of said conductor via, the connection structure extending between an upper semi-conductor layer receiving an active zone of at least one higher level transistor of a microelectronic device comprising several levels of semi-conductor layers arranged one above the other and at least one conducting zone located under the upper level, the method comprising: a) supplying a lower stage provided with at least one first electronic component arranged at least partially in a lower semi-conductor layer resting on a substrate, the electronic component being surmounted by at least one insulating layer and by said conducting zone, then, b) transferring onto the lower stage an upper monocrystalline semi-conductor layer, on an upper face of the at least one insulating layer, then c) producing at least partially said transistor of which the active zone extends in the upper semi-conductor layer and at least one metal region in contact with the active zone, d) carrying out at least one thermal annealing in such a way as to form from said metal region, said contact zone with a metal and semi-conductor compound base and in contact with said upper semi-conductor layer, said contact zone being located in the extension of a conductor via formed before the transferring, said conductor via extending under the upper semi-conductor layer and being arranged in contact with said conducting zone.
    16 . Method according to claim 15 , wherein the producing of the conductor via comprises: the formation through the insulating layer of a conducting element in contact with said conducting zone and said metal region in the extension of this conducting element, said metal region being flush on an upper face of the insulating layer, the transferring in the step b) being carried out in such a way that said metal region is put into contact with a lower face of the upper semi-conductor layer.
    17 . Method according to claim 16 , wherein the formation of the conducting element and of said metal region in its extension comprises steps of: forming the conducting element passing through the insulating layer, removing an upper portion of the conducting element, in such a way as to release a hole in the insulating layer, filling said hole with at least one metal material is such a way as to produce said metal region.
    18 . Method for producing a connection structure comprising a conductor via and a contact zone with a metal and semi-conductor compound in the extension of said conductor via, the connection structure extending between an upper semi-conductor layer receiving an active zone of at least one higher level transistor of a microelectronic device comprising several levels of semi-conductor layers arranged one above the other and at least one conducting zone located under the upper level, the method comprising: a) supplying a lower stage provided with at least one first electronic component arranged at least partially in a lower semi-conductor layer resting on a substrate, the electronic component being surmounted by at least one insulating layer and by said conducting zone, then, b) transferring onto the lower stage an upper monocrystalline semi-conductor layer on an upper face of the at least one insulating layer, then c) producing at least partially said transistor of which the active zone extends in the upper semi-conductor layer and at least one metal region in contact with the active zone, d) carrying out at least one thermal annealing in such a way as to form from said metal region, said contact zone with a metal and semi-conductor compound base and in contact with said upper semi-conductor layer, said contact zone being located in the extension of a conductor via formed after the transferring, said conductor via extending under the upper semi-conductor layer and being arranged in contact with said conducting zone.
    19 . Method according to claim 18 , wherein the producing of the conductor via comprises, steps of: forming of at least one opening passing through the upper semi-conductor layer, depositing of metal material in said opening in such a way as to form the metal region.
    20 . Method according to claim 19 , wherein the producing of the conductor via comprises, prior to the step b) of transferring: the formation through the insulating layer of a conducting element in contact with said conducting zone then with said metal region in the extension of this conducting element, and wherein the adding in the step b) is carried out in such a way that an insulating thickness is retained above an upper end of said conducting element, said opening passing through the upper semi-conductor layer being formed in such a way as to furthermore pass through said insulating thickness and to expose said upper end of said conducting element.
    说明书
    [0001]技术领域
    [0002]本发明属于水泥生产技术领域,具体涉及一种提高还原效率降低水泥窑炉氮氧化物的方法。
    [0003]背景技术
    [0004]传统的水泥生产工艺采用煤粉分级燃烧的方法,在三次风以下区域设置煤粉喷入口,设置煤粉还原区,降低氮氧化物排放。
    [0005]传统的燃煤分级燃烧设置还原区降低氮氧化物的排放,由于还原区域温度低、还原气氛难以控制,存在还原效率低、煤粉燃烧不完全导致燃烧效率低、同时存在碳排放强度高等问题。
    [0006]由于煤粉本身含有氮、硫等元素,导致后续燃烧后会产生氮氧化物和SO 2 、SO 3 等污染物排放。且煤粉中含有的元素比较复杂,会影响熟料的产能,需要对生料配比进行改造,影响了装置的正常稳定运行。
    [0007]另外,现有技术还存在由于烟室流场分布不合理,导致烟室处容易结皮,会堵塞设备,影响装置正常生产。
    [0008]发明内容
    [0009]为了克服以上技术问题,本发明的目的在于提供一种提高还原效率降低水泥窑炉氮氧化物的方法,通过喷入清洁能源,与回转窑来烟气中剩余的氧气进行反应,可有效提高反应温度,并同时增加还原性气氛,提高还原效率。
    [0010]为了实现上述目的,本发明采用的技术方案是:
    [0011]一种提高还原效率降低水泥窑炉氮氧化物的方法,包括以下步骤;
    [0012]S1:在回转窑的分解段距离烟室3-10米处,设置多层清洁能源喷嘴或燃烧器,每层设置多个,根据回转窑的过渡段来的烟气氧含量,对分解段前段部分喷入清洁能源,通过消耗剩余氧气,控制各个喷嘴的阀门开度,通过喷入的清洁能源的流量来控制分解段前段的还原性气氛和温度;分解段后段部分喷入还原性清洁能源,通过阀门控制还原性清洁能源的喷入量,使在煅烧段生成的大量的氮氧化物发生还原反应,生成无污染的N 2 和H 2 O;
    [0013]S2:S1中生成无污染的N 2 和H 2 O进入烟室;在烟室处设置四角切边的方式,布置多层多个还原性清洁能源喷嘴;将整个烟室变为还原区;
    [0014]S3:S2中还原后的气体进入分解炉,将分解炉的三次风处设置多层喷嘴或烧枪,每层布置多个喷嘴和烧枪。
    [0015]所述S1中喷嘴轴向和周向的角度可调。
    [0016]所述S1中在清洁能源喷嘴或燃烧器采用切圆或者对喷的方式布置,加强气流扰动,加强湍流,提高燃烧效率和还原反应效率。
    [0017]所述S1中将氧含量控制在0.5~3%(v),温度控制在1050-1300℃。
    [0018]所述S1中通过阀门控制还原性清洁能源的喷入量,将CO含量控制在10000-50000mg/m 3 ,CHx含量控制在2000-15000ppm。
    [0019]所述S2中,在烟室处,控制温度为1000-1250℃左右。
    [0020]所述S2中四角切边/切圆的方式用于进行气流扰动,加强湍流程度,增强气流混合,一是进一步提高还原效果,二是减少物料在拐角、变径等层流区域的堆积和停留。
    [0021]所述S2通过设置外置式还原炉的方式,进一步增加还原空间,将高氮氧化物的烟气分流至还原炉,还原炉内设置多层清洁能源喷嘴或燃烧器,每层设置多个,将旋风分离预热器来的物料引入,用于控制还原区温度不超温。
    [0022]所述回转窑中的气体运行方向上依次为燃烧段、过渡段和分解段,回转窑中的分解段末端设置烟室,烟室运行方向末端设置分解炉。
    [0023]本发明的有益效果:
    [0024]1、通过清洁能源(天然气、生物质、氢气、生物甲醇等)对燃煤进行替代,可以降低燃料型二氧化碳排放50%-100%;
    [0025]2、通过改造扩大或新增设的还原区域,喷入还原性清洁能源,可有效降低回转窑高温烧成产生的热力型氮氧化物,氮氧化物脱除率可达到50%-100%;减少原SNCR系统的氨水喷入量,或停用原有SNCR系统;
    [0026]3、本发明可提高回转窑分解段及烟室处的温度,为装置扩产提供了条件;
    [0027]4、在烟室处可有效缓解结皮现象,提升装置运行稳定性,减少因为结皮而导致的非计划停工。
    [0028]附图说明
    [0029]图1为本发明的回转窑分解段喷嘴或燃烧器布置图。
    [0030]图2为本发明的烟室处喷嘴或燃烧器布置示意图。
    [0031]图3为本发明的结构示意图一。
    [0032]图4为本发明的结构示意图二。
    [0033]具体实施方式
    [0034]下面结合附图对本发明作进一步详细说明。
    [0035]如图1-图4所示:一种提高还原效率降低水泥窑炉氮氧化物的方法,包括以下步骤;
    [0036]S1,回转窑一般分为冷却段、烧成段、过渡段及分解段,其中分解段的主要作用是进一步分解从分解炉来的物料,降低煅烧能耗及时间。
    [0037]在回转窑分解段离烟室3-10米处,设置多层清洁能源喷嘴或燃烧器,每层设置多个,采用切圆或者对喷的方式布置,设置多层和多个喷嘴或燃烧器,主要是加强炉内气流扰动,使气流混合均匀;根据回转窑过渡段来的烟气氧含量,所述分解段前段部分喷入清洁能源,通过消耗剩余氧气,控制各个喷嘴的阀门开度,通过喷入的清洁能源的流量来控制分解段前段的还原性气氛和温度,将氧含量控制在0.5~3%(v),温度控制在1050-1300℃;分解段后段部分喷入还原性清洁能源,通过阀门控制还原性清洁能源的喷入量,将CO含量控制在10000-50000mg/m 3 ,CHx含量控制在2000-15000ppm,使在煅烧段生成的大量的氮氧化物发生还原反应,生成无污染的N 2 和H 2 O;
    [0038]S2,在烟室处,由于温度比较高,一般在1000-1250℃左右,粉状物料会在设备死角处聚集,长时间后,物料会烧结在一起,形成结皮现象,且操作稍有不慎,结皮会越来越厚,严重时,会堵塞风道,导致装置非正常停工。为此,在烟室处设置四角切边的方式,布置多层多个还原性清洁能源喷嘴;一方面可以加强设备死角处的气流扰动,避免结皮现象,另一方面可以继续增强该区域的还原性,还可将整个烟室变为还原区;
    [0039]受制于装置现有设备空间的影响,无法继续增加还原区域,或可通过设置外置式还原炉的方式,进一步增加还原空间,提高还原区域停留时间。具体为将高氮氧化物的烟气分流至还原炉,还原炉内设置多层清洁能源喷嘴或燃烧器,每层设置多个;为控制还原区温度不超温,可将旋风分离预热器来的物料引入。
    [0040]S3,将三次风处的原煤粉燃烧器替换为多层喷嘴或烧枪,每层布置多个喷嘴和烧枪。
    [0041]本发明采用清洁能源作为还原剂,扩大还原区,较原有还原区域空间增加50-100%,停留时间增加0.5-1倍,由于喷入了清洁能源,与回转窑来烟气中剩余的氧气进行反应,可有效提高反应温度,并同时增加还原性气氛,提高还原效率。具体为在水泥窑烟室处增设还原区,或根据还原特性,在回转窑和分解炉增设一个还原炉,采用以上方法,进一步增加还原性清洁能源的适应性,提高还原反应效率,降低氮氧化物的排放,由于采用清洁能源,无新增其它污染物排放。
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