This manuscript presents JWST MIRI/MRS observations of the central r ≈ 40-240 pc regions of five active galactic nuclei (AGN) spanning a wide range of luminosities (log L_ bol/ erg s^-1≈ 39.8-43.8). Combining multiphase diagnostics from polycyclic aromatic hydrocarbons (PAHs), molecular hydrogen (H_2), and ionized gas at spatial scales of ∼ 4-24 pc, this study presents a spatially resolved investigation into the effects of the two distinct AGN feedback modes–radiative and kinetic–on the surrounding medium. The results indicate that these two feedback modes, associated with AGN irradiation and shock processing, respectively, collectively drive the relative suppression of PAH emission in the nuclear regions of the targets studied here. Moreover, the coexistence of these two AGN feedback modes, especially the shock processing associated with either jets or outflows, in the central regions of AGN naturally explains both the bimodal distribution of PAH band ratios observed in the targets studied here and the seemingly disparate results reported in the literature. Although based on a limited sample, these findings provide new insights into calibrating star-formation rates (SFRs) from PAH emission in AGN, and more importantly, lay the groundwork for a practical framework to diagnose and quantify AGN feedback in the JWST era.

We present James Webb Space Telescope /Mid-Infrared Instrument imaging of eight nearby active galactic nuclei (AGN) from the GATOS (Galactic Activity, Torus, and Outflow Survey) survey to investigate the physical conditions of extended dust in their narrow-line regions (NLRs). In four galaxies (ESO 428-G14, NGC 4388, NGC 3081, and NGC 5728), we detect spatially resolved dust structures extending '100-200 pc along the NLR. In these systems, we find a strong link between the morphology of the dust, the radio ejecta, and the coronal [Si vi ] emission, implying that dust carries imprints of the processes shaping the NLR. Using spatially resolved spectral energy distributions, we show that dust in the NLR has systematically steeper slopes than star-forming clumps. This dust emits at temperatures in the range 150-220 K , at a distance of similar to 150 pc from the nucleus. Using simple models, we show that, even under optimistic assumptions of grain size and AGN luminosity, the excess mid-infrared emission cannot be explained by AGN illumination alone. We interpret this excess heating as in situ . We show that shocks with velocities v(shock) similar to 200-400 km s(-1) in dense gas can close this gap, and in some cases even account for the total observed emission. This, combined with multiple lines of evidence for shocks in these regions, supports a scenario in which shocks not only coexist with dust but may be playing a key role in heating it. Our findings reveal shocks may be an important and previously overlooked driver of extended dust emission in the central hundreds of parsecs in AGN.

We utilize James Webb Space Telescope/Mid Infrared Instrument (JWST/MIRI) Integral Field Unit observations from the Galaxy Activity, Torus and Outflow Survey to investigate the diverse range of ionized outflow rates of obscured active galactic nuclei (AGN) with similar bolometric luminosity and explore potential associations with AGN feedback. We explore spatial correlations between ionized emission potentially associated with fast shocks ([Fe II](5.34 mu m)) and the excitation of H-2. We further constrain our investigation to the inner 400 pc (the nuclear and circumnuclear regions r < 200 pc), and estimate the excitation temperature and column density of H-2 assuming local thermodynamic equilibrium and using the S(1)-S(8) rotational H-2 emission lines visible to JWST/MIRI spectroscopy. We report the molecular gas temperature of the deprojected 400 pc nuclear region to correlate with the ionized mass outflow rate. We also observe a stronger degree of spatial correlation between [Fe II](5.34 mu m) emission and H-2 gas temperature. We observe regions of enhanced [Fe II](5.34 mu m)/[Ar II](6.99 mu m) spatially coincident with the ionization cones of objects with higher ionized outflow rates and [Fe II](5.34 mu m)/[Ar II](6.99 mu m) in the deprojected 400 pc nuclear region to scale positively with both the ionized outflow rate and the estimated molecular gas temperature. We do not observe the estimated jet cavity power within the central 400 pc as strongly correlated with the ionized mass outflow rate or molecular gas temperature of the nuclear region. We take the preceding observations to suggest a higher degree of interaction between AGN outflows and the circumnuclear disk.

This Letter presents an analysis of the infrared (∼3–28 μ m) spectra extracted from the nuclear ( r < 150 pc) regions of four low-luminosity active galactic nuclei (AGN), observed by JWST NIRSpec/integral field unit and MIRI/Medium Resolution Spectroscopy as an extension of the Galaxy Activity, Torus, and Outflow Survey. We find that, compared to higher-luminosity AGN, these low-luminosity AGN exhibit distinct properties in their emission of ionized gas, polycyclic aromatic hydrocarbons (PAHs), and molecular hydrogen (H _2 ). Specifically, the low-luminosity AGN exhibit relatively weak high ionization potential lines (e.g., [Ne V ] and [O IV ]), and the line ratios suggest that fast radiative shocks (with v _s of ∼100s km s ^−1 ) are the primary excitation source of ionized gas therein. Under the low-excitation conditions of their nuclear regions, these low-luminosity AGN generally exhibit a higher fraction of PAHs with large size ( N _C ≳ 200), reflecting the preferential destruction of smaller PAH molecules by AGN feedback. Furthermore, the H _2 transitions in these low-luminosity AGN are not fully thermalized, with slow, plausibly jet-driven molecular shocks (with v _s ≤ 10 km s ^−1 ) likely being the extra excitation source. Taken together with results from the literature, these findings indicate that feedback operates in both low- and high-luminosity AGN, although its impact varies with AGN luminosity. In particular, systematic variations in PAH band ratios are found across AGN, demonstrating the differing influence of feedback in AGN of varying luminosities and highlighting the potential of PAH band ratios as diagnostics for distinguishing kinetic- and radiative-mode AGN feedback.

The Habitable Worlds Observatory (HWO) is a future NASA flagship mission concept identified by the Astro2020 Decadal Survey as the highest priority for large space missions. HWO should conduct "transformative astrophysics" and search for biosignatures in the atmospheres of approximately 25 potentially Earth-like planets. To further the early-stage development of HWO, NASA formed the Science, Technology, Architecture Review Team (START). In turn, START invited the scientific community to join working groups to explore the potential discovery space. In this paper, we present 70 science cases that resulted from this process. The cases address four scientific pillars: growth of galaxies (15 cases), evolution of the elements (13 cases), solar systems in context (32 cases), and living worlds (10 cases). Combined, they would address 27 of the 30 science questions and discovery areas identified by Astro2020. The 140 observing programs needed for the 70 investigations encompass a rich variety of spectroscopic (for 87

The subarcsecond angular resolution and stable background of JWST has given us the first high-fidelity images of the arcsecond-scale environment around Active Galactic Nuclei (AGNs) in the nearby Universe. With mid-infrared (MIR) surface brightness sensitivities that are much deeper than the best ground-based instruments, the Mid-InfraRed Instrument imager (MIRIM) now allows us to understand the structure and thermal properties of dust using information over wavelengths of 5-25 μm, almost all of the MIR range. We present a Cycle 1 JWST MIRIM survey of Seyfert galaxies with the express aim of characterising AGN-heated dust in the central few 100 pcs, and searching for signatures of dust-laden nuclear outflows. This paper outlines the motivation behind the programme, the data reduction and analysis techniques used to isolate the nuclear and extended emission, and a comparison of the observed MIR structures with those seen in other phases (stars, ionised and molecular gas, absorbing dust). In concert with earlier studies that used these data, we conclude that resolved AGN-heated dust is widespread in the Seyfert population, extending out to a few hundred pcs from the nucleus and often displaying a higher surface-brightness compared to the more widespread star-forming dusty circumnuclear disk. Even after accounting for contamination from emission lines in the MIRI filters, we find strong spatial correlations between MIR dust emission and the AGN-ionised gas in the narrow-line region (NLR).

This Letter presents JWST MIRI/Medium-Resolution Spectrometer (MRS) observations of the central r ≈ 40–240 pc regions of five active galactic nuclei (AGN) spanning a wide range of luminosities (log L _bol /erg s ^−1 ≈ 39.8–43.8). Combining multiphase diagnostics from polycyclic aromatic hydrocarbons (PAHs), molecular hydrogen (H _2 ), and ionized gas at spatial scales of ∼4–24 pc, this study presents a spatially resolved investigation into the effects of the two distinct AGN feedback modes—radiative and kinetic—on the surrounding medium. The results indicate that these two feedback modes, associated with AGN irradiation and shock processing, respectively, collectively drive the relative suppression of PAH emission in the nuclear regions of the targets studied here. Moreover, the coexistence of these two AGN feedback modes, especially the shock processing associated with either jets or outflows, in the central regions of AGN naturally explains both the bimodal distribution of PAH band ratios observed in the targets studied here and the seemingly disparate results reported in the literature. Although based on a limited sample, these findings provide new insights into calibrating star formation rates from PAH emission in AGN and, more importantly, lay the groundwork for a practical framework to diagnose and quantify AGN feedback in the JWST era.

The distribution of molecular gas on small scales regulates star formation and the growth of supermassive black holes in galaxy centers. Yet, the role of active galactic nuclei (AGN) feedback in shaping this distribution remains poorly constrained. We investigate how AGNs influence the small-scale structure of molecular gas in galaxy centers by measuring the clumpiness of CO(3 - 2) emission observed with the Atacama Large Millimeter/submillimeter Array (ALMA) in the nuclear regions (50 - 200 pc from the AGNs) of 16 nearby Seyfert galaxies from the Galaxy Activity, Torus, and Outflow Survey (GATOS). To quantify clumpiness we applied three different methods: (1) the median of the pixel-by-pixel contrast between the original and smoothed maps; (2) the ratio of the total excess flux to the total flux, after subtracting the background smoothed emission; and (3) the fraction of total flux coming from clumpy regions, interpreted as the mass fraction in clumps. We find a negative correlation between molecular gas clumpiness and AGN X-ray luminosity (L-X), suggesting that higher AGN activity is associated with smoother gas distributions. All methods reveal a turnover in this relation around L-X = 10(42) erg s(-1), possibly indicating a threshold above which AGN feedback becomes efficient at dispersing dense molecular structures and suppressing future star formation. Our findings provide new observational evidence that AGN feedback can smooth out dense gas structures in galaxy centers.

The distribution of molecular gas on small scales regulates star formation and the growth of supermassive black holes in galaxy centers. Yet, the role of active galactic nuclei (AGN) feedback in shaping this distribution remains poorly constrained. We investigate how AGNs influence the small-scale structure of molecular gas in galaxy centers by measuring the clumpiness of CO(3 − 2) emission observed with the Atacama Large Millimeter/submillimeter Array (ALMA) in the nuclear regions (50 − 200 pc from the AGNs) of 16 nearby Seyfert galaxies from the Galaxy Activity, Torus, and Outflow Survey (GATOS). To quantify clumpiness we applied three different methods: (1) the median of the pixel-by-pixel contrast between the original and smoothed maps; (2) the ratio of the total excess flux to the total flux, after subtracting the background smoothed emission; and (3) the fraction of total flux coming from clumpy regions, interpreted as the mass fraction in clumps. We find a negative correlation between molecular gas clumpiness and AGN X-ray luminosity (LX), suggesting that higher AGN activity is associated with smoother gas distributions. All methods reveal a turnover in this relation around LX = 1042 erg s−1, possibly indicating a threshold above which AGN feedback becomes efficient at dispersing dense molecular structures and suppressing future star formation. Our findings provide new observational evidence that AGN feedback can smooth out dense gas structures in galaxy centers.

We present JWST/MIRI imaging of eight nearby Active Galactic Nuclei (AGN) from the GATOS survey to investigate the physical conditions of extended dust in their narrow line regions (NLRs). In four galaxies (ESO 428-G14, NGC 4388, NGC 3081, and NGC 5728), we detect spatially resolved dust structures extending 100-200 pc along the NLR. In these systems, we find a strong link between the morphology of the dust, the radio ejecta, and the coronal [Si VI] emission, implying that dust carries imprints of the processes shaping the NLR. Using spatially resolved spectral energy distributions, we show that dust in the NLR has systematically steeper slopes than star forming clumps. This dust emits at temperatures in the range 150 - 220 K, at a distance of 150 pc from the nucleus. Using simple models, we show that, even under optimistic assumptions of grain size and AGN luminosity, the excess MIR emission cannot be explained by AGN illumination alone. We interpret this excess heating as in-situ. We show that shocks with velocities of v_ shock∼ 200- 400 km/s in dense gas can close this gap, and in some cases even account for the total observed emission. This, combined with multiple lines of evidence for shocks in these regions, supports a scenario in which shocks not only coexist with dust but may be playing a key role in heating it. Our findings reveal shocks may be an important and previously overlooked driver of extended dust emission in the central hundreds of parsecs in AGN.

Compton-thick Active Galactic Nuclei (AGN) represent one of the most elusive phases of massive black hole growth, yet are expected to contribute substantially to the Cosmic X-ray Background and the integrated growth of massive black holes. NGC 4945 is the closest Compton-thick AGN and amongst the brightest AGN in the hard X-ray sky, making it an important benchmark for more distant Compton-thick AGN. We present the first high-resolution X-ray spectral analysis of NGC 4945 using XRISM/Resolve. The entire 4-15 keV Resolve spectrum, including a strong Fe Kα doublet and weak Compton Shoulder, is well described by a de-coupled dual-obscurer model. The model features a low-covering-factor Compton-thick primary obscurer intersecting the line-of-sight that permits the rapidly variable, direct transmitted coronal continuum to dominate above 10 keV. A Compton-thin secondary reprocessor with a high covering factor dominates the reprocessed emission between ∼4-10 keV. Assuming that virial motion accounts for line broadening, the secondary reprocessor can exist at ∼0.12 pc, and could help explain the weak high-ionisation optical and infrared emission lines observed in NGC 4945. If such obscuration geometries are common among more distant and/or fainter Compton-thick AGN, our results suggest that simpler coupled X-ray spectral modelling could substantially over-estimate Compton-thick covering factors and under-estimate intrinsic X-ray luminosities.

We present a detailed study of the inner regions of NGC 7582, a nearby Seyfert 2 galaxy, from the Galaxy Activity, Torus, and Outflow Survey (GATOS). The galaxy hosts a circumnuclear star-forming disc and an active galactic nucleus (AGN)-driven biconical ionized outflow. Using James Webb Space Telescope Near-Infrared Spectrograph (NIRSpec) and Mid-Infrared Instrument/Medium-Resolution Spectrometer (MIRI/MRS) integral-field spectroscopy, we analyse ionic emission lines spanning a wide range of ionization potentials (IPs, similar to 8-126 eV). Gaussian line-profile fitting reveals kinematic stratification: low-IP species (less than or similar to 20 eV; e.g. [Fe II ], [Ar II ], and [Ne II ]) trace ordered disc rotation with PA similar to -12 +/- 3 degrees, while high-IP species (>= 35 eV; e.g. [O IV ], [Mg IV ], and [Ne V ]) follow the outflow with PA similar to 54 +/- 10 degrees. Outflowing gas exhibits systematically higher velocity dispersions ( 119 +/- 13 km s-1) than the disc ( 78 +/- 11 km s-1), consistent with turbulent or bulk motions. Intermediate-IP lines, [S III ], [Ar III ], and [Ne III ], show contributions from both components, with the outflow characterized by higher dispersion, lower amplitude, and higher velocities in double-Gaussian fits. For these lines, a thin inclined disc plus 1D outflow model enables robust separation and quantification of the disc and outflow velocity fields. The outflow is consistent with a hollow bicone capable of accelerating gas beyond the local escape velocity, implying most material is unlikely to be re-accreted. The ionization cone opening angle shows no dependence on IP, indicating the AGN torus polar regions are largely unobscured. Our study provides new insights into AGN-driven outflows and circumnuclear disc dynamics, offering a framework to disentangle overlapping interstellar medium kinematics in nearby active galaxies.

We present combined James Webb Space Telescope (JWST) NIRSpec and MIRI/MRS integral field spectroscopy data of the nuclear and circumnuclear regions of the highly dust obscured Seyfert 2 galaxy NGC 7582, which is part of the sample of active galactic nucleaus (AGN) in the Galaxy Activity, Torus and Outflow Survey (GATOS). Spatially resolved analysis of the pure rotational H lines (S(1)-S(7)) reveals a characteristic power-law temperature distribution in different apertures, with the two prominent southern star-forming regions exhibiting unexpectedly high molecular gas temperatures, comparable to those in the AGN powered nuclear region. We investigate potential heating mechanisms including direct AGN photoionization, UV fluorescent excitation from young star clusters, and shock excitation. We find that shock heating gives the most plausible explanation, consistent with multiple near- and mid-IR tracers and diagnostics. Using photoionization models from the PhotoDissociation Region Toolbox, we quantify the ISM conditions in the different regions, determining that the southern star-forming regions have a high density (nH similar to 10(5 )cm(-3)) and are irradiated by a moderate UV radiation field (G(0 )similar to 10(3) Habing). Fitting a suite of Paris-Durham shock models to the rotational H lines, as well as rovibrational 1-0 S(1), 1-0 S(2), and 2-1 S(1) H-2 emission lines, we find that a slow ( vs similar to 10 km s(-1)) C-type shock is likely responsible for the elevated temperatures. Our analysis loosely favours local starburst activity as the driver of the shocks and circumnuclear gas dynamics in NGC 7582, though the possibility of an AGN jet contribution cannot be excluded.

Broad-band mid-infrared (MIR) imaging with high-spatial resolution is useful to study extended dust structures in the circumnuclear regions of nearby active galactic nuclei. However, broad-band imaging filters cannot distinguish dust continuum emission from emission lines, and so accounting for the emission line contamination becomes crucial in studying extended dust in these environments. This paper uses Cycle 1 MIR imaging from the James Webb Space Telescope's Mid-Infrared Instrument (JWST/MIRI) and spectroscopy from the Medium-Resolution Spectrometer (JWST/MRS) for 11 local Seyfert galaxies, as part of the Galactic Activity, Torus and Outflow Survey (GATOS). Three of the objects (NGC 3081, NGC 5728, and NGC 7172) exist in both data sets, allowing direct measurement of the line emission using the spectroscopy for these objects. We find that extended MIR emission persists on scales of 100 s of parsecs after the removal of contamination from emission lines. Further, the line contamination levels vary greatly between objects (from 5 per cent to 30 per cent in the F1000W filter), and across filters, so cannot be generalized across a sample and must be carefully treated for each object and band. We also test methods to estimate the line contamination when only MRS spectroscopy or MIRI imaging is available, using pre-JWST ancillary data. We find that these methods estimate the contamination within 10 percentage points. This paper serves as a useful guide for methods to quantify and mitigate for emission line contamination in MIRI broad-band imaging.

With excellent spectral and angular resolutions and, especially, sensitivity, the JWST allows us to observe infrared emission lines that were previously inaccessible or barely accessible. These emission lines are promising for evaluating the physical conditions in different galaxies. Based on MAPPINGS V photoionization models, we systematically analyze the dependence of over 20 mid-infrared (mid-IR) emission lines covered by MIRI on board JWST on the physical conditions of different galactic environments, in particular narrow-line regions in active galactic nuclei (AGN). We find that mid-IR emission lines of highly ionized argon (i.e., [Ar V] 7.90 and 13.10 mu m) and neon (i.e., [Ne V] 14.32 and 24.32 mu m, and [Ne VI] 7.65 mu m) are effective in diagnosing the physical conditions in AGN. We accordingly propose new prescriptions to constrain the ionization parameter (U), peak energy of the AGN spectrum (Epeak), metallicity ( 12+log(O/H) ), and gas pressure (P/k) in AGN. These new calibrations are applied to the central regions of six Seyfert galaxies included in the Galaxy Activity, Torus, and Outflow Survey as a proof of concept. We also discuss the similarity and difference in the calibrations of these diagnostics in AGN of different luminosities, highlighting the impact of hard X-ray emission and particularly radiative shocks, as well as the different diagnostics in star-forming regions. Finally, we propose diagnostic diagrams involving [Ar V] 7.90 mu m and [Ne VI] 7.65 mu m to demonstrate the feasibility of using the results of this study to distinguish galactic regions governed by different excitation sources.

We investigate the capabilities of the mid-infrared instrument (MIRI) of JWST to advance our knowledge of active galactic nucleus (AGN) dust using the spectral fitting technique on an AGN collection of 21 nearby (z < 0.05) AGN (7 type-1 and 14 type-2) observations obtained with the medium resolution spectroscopy (MRS) mode. This collection includes publicly available AGN and data from the collaboration of Galactic Activity, Torus, and Outflow Survey (GATOS). We developed a tool named MRSPSFisol that decomposes MRS cubes into point-like and extended contributions. We found statistically good fits for 12 targets with current AGN dust models. The model that provides good fits chi(2) / dof < 2) for these 12 targets assumes a combination of clumpy and smooth distribution of dust in a flare-disc geometry where the dust grain size is a free parameter. Still, two and one AGN statistically prefer the disc + wind and the classical clumpy torus model, respectively. However, the currently available models fail to reproduce 40 per cent of the targets, likely due to the extreme silicate features not well reproduced by the models and signatures of water-ice and aliphatic hydrocarbon absorption features in most targets. New models exploring, for instance, new chemistry, are needed to explain the complexity of AGN dust continuum emission observed by JWST.

Beyond deepening our understanding of the formation, growth, and evolution of supermassive black holes, it is crucial to uncover the role of feeding and feedback processes from growing black holes (i.e., active galactic nucleus; AGN) in shaping the cosmic ecosystem. Such studies include understanding the dynamics of gas flows in the interstellar (ISM), circumgalactic (CGM), intracluster (ICM), and intergalactic media (IGM). As the output of a sub-group in Habitable Worlds Observatory (HWO) AGN Working Group, this Science Case Development Document (SCDD) proposes to use future HWO observations to solve the following questions. Which mechanism is dominant in triggering inflows/outflows through feedback? How is AGN activity triggered, and is it associated with circumnuclear star formation and what is the overall effect of AGN feedback on star formation (SF)? In AGN feedback, which mode is more influential and does AGN feedback operate similarly or differently in the local universe and at high redshift? To answer these questions, this SCDD proposes to use potential HWO observations as follows. Resolve and characterize the spatial distribution of ionized and cold/warm molecular gas, especially those in inflows/outflows; Explore the spatial coupling and potential stratification of multi-phase inflows/outflows on different physical scales and their resolved and global correlations with AGN and/or SF activities; Investigate whether corresponding outflows/jets induce shocks and/or fluctuations that trigger or suppress the formation of molecular clouds and hence new stars. Specifically, HWO's capabilities will enable us to achieve the above scientific goals while existing facilities lack the required combination of high-throughput ultraviolet (UV) and near-infrared (NIR) integral field unit (IFU) capabilities with simultaneously sufficient spatial resolution and sensitivity.

We present a 19.7-214 mu m imaging atlas of local (4-181 Mpc; median 43 Mpc) active galactic nuclei (AGN) observed with FORCAST and HAWC+ on board the SOFIA telescope with angular resolutions similar to 3 ''-20 ''. This atlas comprises 22 Seyferts (17 Type 2 and five Type 1) with a total of 69 images, 41 of which have not been previously published. The AGN span a range of luminosities of log10(L-bol[erg s(-1)])=[42,46] with a median of log10(L-bol[erg s(-1)])=44.1 +/- 1.0. We provide the total fluxes of our sample using aperture photometry for point-source objects and a 2D Gaussian fitting for objects with extended host galaxy emission, which was used to estimate the unresolved nuclear component. Most galaxies in our sample are pointlike sources; however, four sources (Centaurus A, Circinus, NGC 1068, and NGC 4388) show extended emission in all wavelengths. The 30-40 mu m extended emission in NGC 4388 is coincident with the narrow-line region at PA similar to 50 degrees, while the dusty extension at longer wavelengths arises from the host galaxy at PA similar to 90 degrees. Our new observations allow us to construct the best-sampled parsec-scales (spectral energy distributions, SEDs) available between 30 and 500 mu m for a sample of nearby AGN. We estimate that the average peak wavelength of the nuclear SEDs is similar to 40 mu m in nu F-nu, which we associate with an unresolved extended dusty region heated by the AGN.

We utilize James Webb Space Telescope (JWST) Mid Infrared Instrument (MIRI) integral field unit observations to investigate the behavior and excitation of H _2 in the nearby Seyfert galaxies NGC 3081 and NGC 5506, both part of the Galactic Activity, Torus, and Outflow Survey (or GATOS). We compare population levels of the S(1) to S(8) rotational H _2 emission lines visible to JWST/MIRI spectroscopy to models assuming local thermodynamic equilibrium (LTE), in order to estimate the column density and thermal scaling of the molecular gas. For the nuclear regions, we incorporate Very Large Telescope Spectrograph for INtegral Field Observations in the Near Infrared (or VLT/SINFONI) K -band observations to estimate population levels for available rovibrational H _2 emission lines, and compare the resultant population curves to non-LTE radiative transfer models and shock modeling. We report a differing set of prominent active galactic nuclei (AGN)-driven excitation mechanisms between the two galaxies. For NGC 3081, we find that a non-LTE radiative transfer environment is adequate to explain observations of the nuclear region, indicating that the primary mode in which the AGN transfers excitation energy is likely irradiation. We estimate the extent of AGN photoionization along the ionization bicone to be ≈330 pc. In contrast, for NGC 5506, we find a shock scenario to be a more plausible excitation mechanism, a conclusion bolstered by an observed spatial correlation between higher-energy rotational H _2 and [Fe II ] _5.34 _μ _m emission. In addition, we identify potential nuclear H _2 outflows resulting from an interaction between the ionization bicone and the rotational disk. By isolating the outflowing component of the H _2 emission, we estimate the warm molecular mass outflow rate to be 0.07 M _⊙ yr ^−1 .