The goal of this stydy was to explore the potential of the enhanced corrosion resistance of Ti(N,O) cathodic arc evaporation-coated 304L stainless steel using oxide nano-layers deposited by atomic layer deposition (ALD). In this study, we deposited Al2O3, ZrO2, and HfO2 nanolayers of two different thicknesses by ALD onto Ti(N,O)-coated 304L stainless steel surfaces. XRD, EDS, SEM, surface profilometry, and voltammetry investigations of the anticorrosion properties of the coated samples are reported. The amorphous oxide nanolayers homogeneously deposited on the sample surfaces exhibited lower roughness after corrosion attack compared to the Ti(N,O)-coated stainless steel. The best corrosion resistance was obtained for the thickest oxide layers. All samples coated with thicker oxide nanolayers augmented the corrosion resistance of the Ti(N,O)-coated stainless steel in a saline, acidic, and oxidising environment (0.9% NaCl + 6% H2O2, pH = 4), which is of interest for building corrosion-resistant housings for advanced oxidation systems such as cavitation and plasma-related electrochemical dielectric barrier discharge for breaking down persistent organic pollutants in water.

In this paper, a novel biocompatible alloy defined as FeMoTaTiZr was obtained and functionalized by hydroxyapatite-based coatings (HAP) in order to increase their biocompatibility, bioactivity, and resistance to corrosion for to be used as bone implants. To obtain the surface with antibacterial properties, the HAP coatings were doped with small amount of Zn. The alloy was prepared using the VAR (Vacuum Arc Remelting) equipment, while the coatings by RF magnetron sputtering method. The EDS analysis confirmed the presence of Ca and P in the case of all developed coatings, having Ca/P ratio ranged from 1.69 (undoped HAP) to 1.96 (Zn doped HAP). The (Ca+Zn)/P ration was of about 2.15 for the Zn doped HAP coatings. The XRD and ATR-FTIR investigations confirmed the presence of calcium phosphate phases. After coating with HAP, the roughness of uncoated substrates increased with 1.4 times, and it was considerably increased by the Zn addition with 2.4 times. The electrochemical tests showed that the un-doped HAP exhibited good corrosion behavior, while Zn doped HAP coatings have a high dissolution rate in fetal bovine serum, being more proper as a biodegradable material.

SiC- and Ag-SiC-doped hydroxyapatite (HA) coatings were deposited via magnetron sputtering aiming at increased corrosion protection of Ti-10Nb-10Zr-5Ta alloy in simulated body fluid environment and superior mechanical properties compared to plain hydroxyapatite. The coatings had a total thickness of about 350 nm. The X ray diffraction patterns indicate that HA coatings are polycrystalline with a hexagonal structure and the addition of SiC determined the coating amorphization. All coatings presented a lower roughness compared to the Ti alloy and were hydrophilic. Ag-SiC-HA coating presented the best corrosion resistance and tribological parameters. All coatings were biocompatible, as ascertained via indirect cytocompatibility studies conducted on Vero cells.

The presence and detection of persistent pharmaceutical pollutants (PPPs) in aquatic environments requires urgent remediation. C-N-TiO2 was prepared by sol-gel method and immobilised on Ti mesh by dip-coating technique followed by pyrolysis in the furnace at 350 & DEG;C for 105 minutes. The Ti/C-N-TiO2 photocatalyst were characterised by SEM, EDS, XRD, Raman spectroscopy, and XPS. An optimised DCDBD system alone or combined with Ti/CN-TiO2 catalysts were compared for the degradation of sulfamethoxazole (SMX) simulated wastewater at the applied conditions. The SEM-EDS results showed that C, N, and Ti were all present in the C-N-TiO2 nano catalyst layer supported upon Ti mesh. XPS results revealed existence of Ti in + 4 oxidation states despite the addition carbon and nitrogen. The XRD and Raman patterns confirmed the formation of anatase as dominant phase. The antibacterial tests of Ti/C-N-TiO2 films showed an excellent effect on E. coli inhibition. The degradation of SMX with DCDBD and DCDBD/C-N-TiO2/Ti-mesh systems followed first-order reaction and complete mineralisation of the pollutants was achieved after 30 and 60 min of plasma run at rate constants of 3.79 x10 -2 min-1 (R 2 = 0.999) and 2.18 x10 -2 min-1 (R 2 = 0.997), respectively. The energy yield G 50 required for the degradation of 50% SMX reached 34.64 g/kWh corresponding to an electrical efficiency per order (EE/O) of 40.527 kWh/m3 order1 with DCDBD alone within 18 min, and 19.787 g/kWh with DCDBD/Ti/C-N-TiO2 system corresponding to an EE/O of 70.458 kWh/m3 order1 after 32 min. Different recalcitrant degradation intermediate by-products were detected by HPLC/MS and their degradation pathways proposed. Therefore, this study offers a novel advanced oxidation technology for the remediation of SMX from aqueous solution.

The activities presented under this paper were focused on designing, manufacturing, testing and evaluation of a metallic antenna reflector for space applications. The main challenge was to obtain a low mass, while maintaining the reflector capability to withstand the mechanical loads encountered during the launching phase, as well as the harsh space environment with significant temperature variations, without any detrimental effect over the dimensional stability of the reflective surface. The chosen material was titanium alloy for the reflector and stainless steel for fasteners and mounting supports. Manufacturing parameters have been investigated aiming for low internal stresses during processing and to obtain the best results in terms of dimensional accuracy and surface roughness. One of the five analysed reflector architectures (reflector breadboards) was selected and manufactured using two different finishing operations, milling and turning, the latter being the one presenting the best results. Dimensional accuracy of the reflector breadboard, before and after vibration and environmental tests, was found to be smaller than the imposed requirements, thus validating the reflector proposed design. After the breadboarding activity, an optimized version of the antenna reflector (demonstrator), also validated by structural analysis, was developed. Unfortunately, the measured profile deviation of the demonstrator was higher than the imposed requirements (by 50%), mainly due to internal stresses during mechanical processing of the new geometry. Before the experimental evaluation of the reflector demonstrator, a surface coating was developed and applied to the reflective surface of the demonstrator. Despite the profile deviation, the demonstrator meets the imposed mechanical requirements and offers important lessons to be applied in the future development activities.

A new tangential gamma-ray spectrometer has been developed for fast ion measurements in deuterium and deuterium-tritium plasmas of the Joint European Torus (JET). The instrument is based on a LaBr3 crystal with a photo-multiplier tube and replaces a pre-existing bismuth germanate detector, providing enhanced energy resolution and a counting rate capability in the MHz range. The line of sight is equipped with a LiH attenuator, which reduces the background due to 14 MeV neutron interactions with the crystal by more than two orders of magnitude and enables the observation of gamma-ray emission from confined α particles in JET deuterium-tritium plasmas. Thanks to its tangential line of sight, the detector can distinguish co- and counter-passing ions. The performance of the instrument is demonstrated through the results of recent JET fast ion experiments in deuterium plasmas.

In this paper, a novel biocompatible alloy defined as FeMoTaTiZr was obtained and functionalized by hydroxyapatite-based coatings (HAP) in order to increase their biocompatibility, bioactivity, and resistance to corrosion for to be used as bone implants. To obtain the surface with antibacterial properties, the HAP coatings were doped with small amount of Zn. The alloy was prepared using the VAR (Vacuum Arc Remelting) equipment, while the coatings by RF magnetron sputtering method. The EDS analysis confirmed the presence of Ca and P in the case of all developed coatings, having Ca/P or Ca/(P+Zn) ratio of about 1.70 and 1.66, respectively. The XRD and ATR-FTIR investigations confirmed the presence of calcium phosphate phases. The roughness of uncoated substrates increased after coating with HAP, and it was considerably increased by the Zn addition. The electrochemical tests showed that the un-doped HAP exhibited good corrosion behavior, while Zn doped HAP coatings have a high dissolution rate in fetal bovine serum, being more proper as a biodegradable material.

Zr-based nitrides and oxynitrides were deposited by reactive cathodic arc evaporation in monolayer and double-layer structures with the aim of increasing the corrosion protection of 304L stainless steel (SS) in a biomedical aggressive environment. All coatings had a total thickness of 1.2 µm. Compared to the bare substrate, the surface roughness of the coated samples was higher, the presence of microdroplets being revealed by scanning electron micrography (SEM). The X-ray diffraction investigation of the ZrN phases revealed that the peaks shifted towards lower Bragg angles and the lattice constants increased as a result of Si and O2 inclusion in ZrN lattice, and of the ion bombardment characteristic of the cathodic arc method, augmented by the applied bias substrate. SS/ZrSiN/ZrSi(N,O) showed the best corrosion performance in an acidic environment (0.9% NaCl and 6% H2O2; pH = 4), which was ascribed to the blocking effect of the interfaces, which acted as a corrosion barrier for the electrolyte ingress. Moreover, the aforementioned bilayer had the highest amount of Si and O in the composition of the top layer, forming a stable passive layer with beneficial effects on corrosion protection.

The reactive cathodic arc deposition technique was used to produce Ti nitride and oxynitride coatings on 304 stainless steel substrates (SS). Both mono (SS/TiN, SS/TiNO) and bilayer coatings (SS/TiN/TiNO and SS/TiNO/TiN) were investigated in terms of elemental and phase composition, microstructure, grain size, morphology, and roughness. The corrosion behavior in a solution consisting of 0.10 M NaCl + 1.96 M H2O2 was evaluated, aiming for biomedical applications. The results showed that the coatings were compact, homogeneously deposited on the substrate, and displaying rough surfaces. The XRD analysis indicated that both mono and bilayer coatings showed only cubic phases with (111) and (222) preferred orientations. The highest crystallinity was shown by the SS/TiN coating, as indicated also by the largest grain size of 23.8 nm, which progressively decreased to 16.3 nm for the SS/TiNO monolayer. The oxynitride layers exhibited the best in vitro corrosion resistance either as a monolayer or as a top layer in the bilayer structure, making them a good candidate for implant applications.

Alloyed TiSi-stainless steel carbide coatings were deposited by cathodic arc method on Si (100) and C45 steel substrates, from TiSi alloy and stainless-steel cathodes in C2H2 atmosphere. Different compositions were obtained by modifying the C2H2 mass flow rate and the arc current at the stainless-steel cathode. The coatings were investigated for elemental and phase composition, chemical bonding state, crystalline structure, morphology, hardness, adhesion strength, friction and wear performance. The coatings were found to possess a composite structure consisting of crystalline metallic carbide and amorphous free carbon. For carbon content higher than 43 at. %, the coatings exhibited a poor crystallinity and a random texture. All deposited coatings showed compact cross-sectional morphologies. It has been shown that the friction and wear performance of the carbide coatings were strongly dependent on the carbon content, such as the overstoichiometric carbide coatings presented superior tribological characteristics compared to the understoichiometric coatings. Depending on the carbon content, different wear mechanisms were identified: adhesive and oxidative wear for the coatings with understoichiometric carbide coatings, while for the overstoichiometric ones the adhesive and polishing wear was evidenced. The coatings containing the highest carbon content of similar to 64 at. % provided the best wear resistance (wear rate of 1.1 x 10(-6) mm(3)N(-1)m(-1)) and the lowest friction coefficient (0.15).

In this work, the influence of NbZr and ZrSi addition to TiCN coatings are studied, aiming for their use as protective layers for parts subjected to severe corrosion and wear. The coatings with C/N ratios ranging from 0.4 to 2.5 were deposited using the cathodic arc technique in a mixture of N-2 and CH4 gases, on 316 stainless steel discs and Si (111) wafers. All the coatings exhibited residual compressive stresses, with values ranging from approximately-2.4 GPa to -3.5 GPa. The addition of Si led to an increase in hardness, regardless of the C/N ratio. All coatings with high C/N ratio (similar to 2.5) presented slightly lower stress values and superior performance in 3.5% NaCl corrosive solutions, the best performance being obtained for the TiSiZrCN coating, which exhibited the highest protective efficiency to corrosion (97.8%), due to its low corrosion current density (1.734 mu A/cm(2)) and high polarization resistance (31.775 k Omega). The tribological tests, performed at 23 degrees C and 250 degrees C, indicated that abrasion and oxidation were the predominant wear mechanism for all coatings. At 23 degrees C, the friction coefficients of the coated specimens were significantly lower than those of the uncoated samples. When the collective performance across all of the experimental parameters was assessed, the coatings with C/N of about 2.5 proved to be the most suitable candidates to be used in severe service conditions.

Transport modelling of Joint European Torus (JET) dimensionless collisionality scaling experiments in various operational scenarios is presented. Interpretative simulations at a fixed radial position are combined with predictive JETTO simulations of temperatures and densities, using the TGLF transport model. The model includes electromagnetic effects and collisions as well as E ⃗ × B ⃗ shear in Miller geometry. Focus is on particle transport and the role of the neutral beam injection (NBI) particle source for the density peaking. The experimental 3-point collisionality scans include L-mode, and H-mode (D and H and higher beta D plasma) plasmas in a total of 12 discharges. Experimental results presented in (Tala et al 2017 44th EPS Conf. ) indicate that for the H-mode scans, the NBI particle source plays an important role for the density peaking, whereas for the L-mode scan, the influence of the particle source is small. In general, both the interpretative and predictive transport simulations support the experimental conclusions on the role of the NBI particle source for the 12 JET discharges.

Fusion performance in tokamaks hinges critically on the efficacy of the edge transport barrier (ETB) in suppressing energy losses. The new concept of 'fingerprints' is introduced to identify the instabilities that cause transport losses in the ETBs of many of today's experiments, from among widely posited candidates. Analysis of the gyrokinetic-Maxwell equations and gyrokinetic simulations of experiments reveals that each mode type produces characteristic ratios of transport in the various channels: density, heat, and impurities. This, together with experimental observations of transport in some channel or of the relative size of the driving sources of channels, can identify or determine the dominant modes causing energy transport. In multiple H-mode cases with edge-localized modes that are examined, these fingerprints indicate that magnetohydrodynamic (MHD)-like modes are apparently not the dominant agent of energy transport; rather, this role is played by micro-tearing modes (MTMs) and electron temperature gradient (ETG) modes, and in addition, possibly by ion temperature gradient/ trapped electron modes (ITG/TEM) on JET (Joint European 'Torus). MHD-like modes may dominate the electron particle losses. Fluctuation frequency can also be an important means of identification, and is often closely related to the transport fingerprint. The analytical arguments unify and explain previously disparate experimental observations on multiple devices, including DIII-D, JET, and ASDEX-U. Detailed simulations of two DIII-D ETBs also demonstrate and corroborate this.

In this paper, we analyze heat transport in the JET tokamak using data from its high resolution ECE diagnostic and analyses based on the transfer entropy (TE). The analysis reveals that heat transport is not smooth and continuous, but is characterized by 'trapping regions' separated by `minor transport barriers'. Meat may 'jump over' these barriers and when the heating power is raised, this 'jumping' behavior becomes more prominent. To check that our results are relevant for global heat transport, we deduced an effective diffusion coefficient from the TE results. Both its value and overall radial variation are consistent with heat diffusivities reported in literature. The detailed radial structure of the effective diffusion coefficient was shown to be linked to the mentioned minor transport barriers.

Results from two different sets of JET experiments are presented.In experiments in which toroidicity-induced Alfvén eigenmodes (TAEs) localized at different radial locations had the same frequencies and toroidal mode numbers, the occurrence of enhanced losses after the excitation of TAEs in the core of the plasma was observed.On the contrary, enhanced losses were not observed if the TAEs localized at different radial locations had different frequencies and toroidal mode numbers.Numerical modeling indicates that, in the first set of experiments, the enhanced losses were caused by a combined effect of the TAEs localized at different radial locations.The TAEs localized in the plasma core transported energetic ions from the core to outer regions of the plasma.Then, the TAEs localized in outer regions of the plasma interacted with these ions just transported by the core-localized TAEs causing a further radial displacement of the ions to the plasma edge.This process eventually ends up causing the loss of the resonant ions.In the second set of experiments, it was found that TAEs localized in the plasma core and in outer regions did not interact with the same ions and so no enhanced losses were measured.Sheared profiles of the safety factor combined with flat mass density profiles lead to larger differences on the frequencies of the TAEs localized at different radial locations, eventually avoiding loss of energetic ions through the described mechanism.

In this study, beryllium tiles from Joint European Torus (JET) vacuum vessel wall were analysed and compared regarding their position in the vacuum vessel and differences in the exploitation conditions during two campaigns of ITER-Like-Wall (ILW) in 2011-2012 (ILW1) and 2013-2014 (ILW2) Tritium content in beryllium samples were assessed. Two methods were used to measure tritium content in the samples - dissolution under controlled conditions and tritium thermal desorption. Prior to desorption and dissolution experiments, scanning electron microscopy and energy dispersive x-ray spectroscopy were used to study structure and chemical composition of plasma-facing-surfaces of the beryllium samples. Experimental results revealed that tritium content in the samples is in range of 2.10(11)-2.10(13) tritium atoms per square centimetre of the surface area with its highest content in the samples from the outer wall of the vacuum vessel (up to 1.9.10(13) atoms/cm(2) in ILW1 campaign and 2.4.10(13) atoms/cm(2) in ILW2). The lowest content of tritium was found in the upper part of the vacuum vessel (2.0.10(12) atoms/cm(2) and 2.0.10(11) atoms/cm(2) in ILW1 and ILW2, respectively). Results obtained from scanning electron microscopy has shown that surface morphology is different within single tile, however if to compare two campaigns main tendencies remains similar.

The first divertor was installed in the JET machine between 1992 and 1994 and was operated with carbon tiles and then beryllium tiles in 1994-5. Post-mortem studies after these first experiments demonstrated that most of the impurities deposited in the divertor originate in the main chamber, and that asymmetric deposition patterns generally favouring the inner divertor region result from drift in the scrape-off layer. A new monolithic divertor structure was installed in 1996 which produced heavy deposition at shadowed areas in the inner divertor corner, which is where the majority of the tritium was trapped by co-deposition during the deuterium-tritium experiment in 1997. Different divertor geometries have been tested since such as the Gas-Box and High-Delta divertors; a principle objective has been to predict plasma behaviour, transport and tritium retention in ITER. Transport modelling experiments were carried out at the end of four campaigns by puffing C-13-labelled methane, and a range of diagnostics such as quartz-microbalance and rotating collectors have been installed to add time resolution to the post-mortem analyses. The study of material migration after D-D and D-T campaigns clearly revealed important consequences of fuel retention in the presence of carbon walls. They gave a strong impulse to make a fundamental change of wall materials. In 2010 the carbon divertor and wall tiles were removed and replaced with tiles with Be or W surfaces for the ITER-Like Wall Project.

Data on erosion and melting of beryllium upper limiter tiles, so-called dump plates (DP), are presented for all three campaigns in the JET tokamak with the ITER-like wall. High-resolution images of the upper wall of JET show clear signs of flash melting on the ridge of the roofshaped tiles. The melt layers move in the poloidal direction from the inboard to the outboard tile, ending on the last DP tile with an upward going waterfall-like melt structure. Melting was caused mainly by unmitigated plasma disruptions. During three ILW campaigns, around 15% of all 12376 plasma pulses were catalogued as disruptions. Thermocouple data from the upper dump plates tiles showed a reduction in energy delivered by disruptions with fewer extreme events in the third campaign, ILW-3, in comparison to ILW-1 and ILW-2. The total Be erosion assessed via precision weighing of tiles retrieved from JET during shutdowns indicated the increasing mass loss across campaigns of up to 0.6 g from a single tile. The mass of splashed melted Be on the upper walls was also estimated using the high-resolution images of wall components taken after each campaign. The results agree with the total material loss estimated by tile weighing (similar to 130 g). Morphological and structural analysis performed on Be melt layers revealed a multilayer structure of re-solidified material composed mainly of Be and BeO with some heavy metal impurities Ni, Fe, W. IBA analysis performed across the affected tile ridge in both poloidal and toroidal direction revealed a low D concentration, in the range 1-4 x 10(17) D atoms cm(-2).

Beryllium limiter marker tiles were exposed to plasma in the Joint European Torus to diagnose the erosion of main chamber wall materials. A limiter marker tile consists of a beryllium coating layer (7-9 mu m) on the top of bulk beryllium, with a nickel interlayer (2-3 mu m) between them. The thickness variation of the beryllium coating layer, after exposure to plasma, could indicate the erosion measured by ion beam analysis with backscattering spectrometry. However, interpretations from broad beam backscattering spectra were limited by the non-uniform surface structures. Therefore, micro-ion beam analysis (mu-IBA) with 3 MeV proton beam for Elastic back scattering spectrometry (EBS) and PIXE was used to scan samples. The spot size was in the range of 3-10 mu m. Scanned areas were analysed with scanning electron microscopy (SEM) as well. Combining results from mu-IBA and SEM, we obtained local spectra from carefully chosen areas on which the surface structures were relatively uniform. Local spectra suggested that the scanned area (approximate to 600 mu m x 1200 mu m) contained regions with serious erosion with only 2-3 mu m coating beryllium left, regions with intact marker tile, and droplets with 90% beryllium. The nonuniform erosion, droplets mainly formed by beryllium, and the possible mixture of beryllium and nickel were the major reasons that confused interpretation from broad beam EBS.

EDGE2D-EIRENE (the ‘code’) simulations show that radial electric field, Er, in the near scrape-off layer (SOL) of tokamaks can have large variations leading to a strong local E × B shear greatly exceeding that in the core region. This was pointed out in simulations of JET plasmas with varying divertor geometry, where the magnetic configuration with larger predicted near SOL Er was found to have lower H-mode power threshold, suggesting that turbulence suppression in the SOL by local E × B shear can be a player in the L–H transition physics (Delabie et al 2015 42nd EPS Conf. on Plasma Physics (Lisbon, Portugal, 22–26 June 2015) paper O3.113 (http://ocs.ciemat.es/EPS2015PAP/pdf/O3.113.pdf), Chankin et al 2017 Nucl. Mater. Energy 12 273). Further code modeling of JET plasmas by changing hydrogen isotopes (H–D–T) showed that the magnitude of the near SOL Er is lower in H cases in which the H-mode threshold power is higher (Chankin et al 2017 Plasma Phys. Control. Fusion 59 045012). From the experiment it is also known that hydrogen plasmas have poorer particle and energy confinement than deuterium plasmas, consistent with the code simulation results showing larger particle diffusion coefficients at the plasma edge, including SOL, in hydrogen plasmas (Maggi et al 2018 Plasma Phys. Control. Fusion 60 014045). All these experimental observations and code results support the hypothesis that the near SOL E × B shear can have an impact on the plasma confinement. The present work analyzes neutral ionization patterns of JET plasmas with different hydrogen isotopes in L-mode cases with fixed input power and gas puffing rate, and its impact on target electron temperature, Te, and SOL Er. The possibility of a self-feeding mechanism for the increase in the SOL Er via the interplay between poloidal E × B drift and target Te is discussed. It is also shown that reducing anomalous turbulent transport coefficients, particle diffusion and electron and ion heat conductivities, leads to higher peak target Te and larger Er, suggesting the possibility of a positive feedback loop, under an implicitly made assumption that the E × B shear in the SOL is capable of suppressing turbulence.