Probing static disorder in Arrhenius kinetics by single-molecule force spectroscopy.
Proceedings of the National Academy of Sciences of the United States of America, no. 25 (2010): 11336-11340
The widely used Arrhenius equation describes the kinetics of simple two-state reactions, with the implicit assumption of a single transition state with a well-defined activation energy barrier DeltaE, as the rate-limiting step. However, it has become increasingly clear that the saddle point of the free-energy surface in most reactions is ...更多
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