Ring-Opening Reactions of beta-Lactones with Activated Anions.

Zbigniew Jedliński,P.-E. Werner,T. Wadsten,G. Bidló,G. Liptay,Jorma Mattinen,Alexander Senning,Xin-Kan Yao,Hong-Gen Wang,J.-P. Tuchagues,Mattias Ögren

Acta Chemica Scandinavica（1999）

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摘要

The mechanistic aspects of beta-butyrolactone ring-opening reactions with various activated anions, their regioselectivity and stereochemistry are discussed. The facile synthesis of biomimetic polyesters having similar microstructure and properties as produced in Nature, such as poly-(R)-3-hydroxybutanoic acid, has been accomplished.

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