Rhodium-catalyzed heterogeneous enantioselective hydrogenation of 3,5-di-(trifluoromethyl)-acetophenone

Journal of Molecular Catalysis A: Chemical（2004）

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摘要

In the asymmetric hydrogenation of 1, replacement of CD by its ether derivatives resulted in the inversion of enantioselectivity from (S)-2 to (R)-2.

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关键词

Asymmetic hydrogenation,3,5-Di-(trifluoromethyl)-acetophenone,Rh/alumina,Cinchonidine derivatives,Inversion of enantioselectivity

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