Stereospecific tetracyclization of icosatetraenes via Mn(III) promoted oxidative free-radical cyclization

Phillip A. Zoretic,Xiaoyu Weng,Myron L. Caspar,Donald G. Davis

TETRAHEDRON LETTERS（1992）

引用 64|浏览14

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摘要

A stereospecific oxidative free-radical cyclization of polyene 10a to the D-homo-5-alpha-androstane system 11a containing seven asymmetric centers is reported.

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free radical

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