V2O5·0.6H2O nanoribbons as cathode material for asymmetric supercapacitor in K2SO4 solution

Electrochemistry Communications(2009)

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摘要
V2O5·0.6H2O nanoribbons were prepared and their electrochemical behaviors in K2SO4 aqueous solution were investigated. Results show for the first time that K+ ions could intercalate/deintercalate reversibly in the V2O5·0.6H2O lattice. An asymmetric supercapacitor activated carbon/0.5mol/l K2SO4/V2O5·0.6H2O was successfully assembled, which could be cycled reversibly in the voltage region of 0–1.8V. This supercapacitor presents an energy density of 29.0Wh/kg based on the total mass of the active electrode materials, a very good rate behavior with energy density of 20.3Wh/kg at power density of 2kW/kg, and also a rather good cycling performance.
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关键词
Supercapacitor,V2O5·0.6H2O,K+,Intercalation,Aqueous electrolyte
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