Fast-Atom-Bombardment Mass-Spectrometry In The Stereochemical Characterization Of A New Group Of C30 Nuphar Alkaloids

O. Bortolini, A. Labianco,O. Curcuruto,P. Traldi, J. T. Wròbel, A. Iwanow

RAPID COMMUNICATIONS IN MASS SPECTROMETRY（1993）

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摘要

A new group of thio-C30 nuphar alkaloids has been obtained from the three main stereoisomers by complete oxidation of the sulphur and both the tertiary nitrogen sites. High-resolution mass spectrometry and metastable-ion decomposition analysis were used to distinguish and characterize diastereoisomers.

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mass spectrometry,fast atom bombardment

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