Structural analysis of Pt(111)c(√3×5)rect.–CO using photoelectron diffraction

Core level shift scanned-energy mode photoelectron diffraction using the two distinct components of the C 1s emission has been used to determine the structure of the Pt(111)c(√3×5)rect.–CO phase formed by 0.6ML of adsorbed CO. The results confirm earlier assignments of these components to CO in atop and bridging sites, further confirm that the best structural model involves a 2:1 occupation ratio of these two sites, and provides quantitative structural parameter values. In particular the Pt–C chemisorption bondlengths for the atop and bridging sites are, respectively, 1.86±0.02Å and 2.02±0.04Å. These values are closely similar to those found in the 0.5ML coverage c(4×2) phase, involving an atop:bridge occupation ratio of 1:1, obtained in earlier quantitative low energy electron diffraction studies. The results also indicate a clear tilt of the molecular axis of atop CO species in this compression phase, consistent with the finding of an earlier electron-stimulated desorption ion angular distribution investigation.