Alkene Epoxidation Using Ni(II) Complexes of Chiral Cyclams

Joanne F. Kinneary,Thomas R. Wagler,Cynthia J. Burrows

TETRAHEDRON LETTERS（1988）

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摘要

A series of Ni(II)-cyclam complexes bearing substituents on the macrocyclic ring are active catalysts for olefin epoxidation. Mechanistic studies suggest important differences from heme catalysts.

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