Assembly of two low-dimensional coordination polymers from Ag(I) and Cd(II) and 2,3-bis(2-pyridyl)pyrazine

Inorganica Chimica Acta(2010)

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摘要
Based on polydentate nitrogen heterocycle ligand bis-2,3-(2-pyridyl)pyrazine(2,3-bpp), two new complexes [Ag(bpy)(NO3)]2 (1) and [Cd(bpp)(NO3)2]n (2) are assembled under the same conditions. Because of the cation effect, 1 is a dinuclear discrete compound, while 2 presents 1D chain-like structure.
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关键词
Ag(I) and Cd(II) complexes,2,3-Bis(2-pyridyl)pyrazine,X-ray single-crystal structure,Antibacterial activities,Luminescence
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