Electronegativity difference, atomic size parameter and widths of supercooled liquid regions of Sb2S3–As2S3–Sb2Te3 glasses

K. N'Dri,D. Houphouet-Boigny,J.C. Jumas,J. Olivier-Fourcade

Journal of Non-Crystalline Solids（2011）

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摘要

Electronegativity difference Δx, atomic size parameter δ and width of supercooled liquid region (ΔTx=Tx−Tg, where Tx is the onset crystallization temperature and Tg the glass transition temperature) are analysed for glasses of the ternary system Sb2S3–As2S3–Sb2Te3 as a function of arsenic atomic percentage.

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关键词

Glasses,Electronegativity difference,Atomic size parameter,Width of supercooled liquid region

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