Light-Induced Chirality in a Liquid Crystal

H. Takezoe, S.-W. Choi, T. Izumi, Y. Hoshino, Y. Takanishi, K. Ishikawa, J. Watanabe

Synfacts（2006）

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摘要

Upon irradiation of the bent-shaped mesogen with circular polarized light (CPL) in resonance with the azo group absorption, uniform chiral liquid crystalline phase domains of a given handedness are reversibly obtained. CPL stimulation achieves very large ee values (up to ca. 100%) of either enantiomer by this nucleated photoresolution.

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