Crystal Engineering In The Solid-State Photochemistry Of Cyclohexenones

Z. Q. Jiang,John R. Scheffer,Anthony S. Secco,James Trotter

TETRAHEDRON LETTERS（1981）

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摘要

Previous results from our laboratory plus a simple conformational analysis argument lead to the prediction that irradiation of cyclohexenone 1 in the solid state will give ketol 2 . An independent synthesis of 2 plus a determination of the solid state conformation of 1 by X-ray crystallography show this prediction to be correct.

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