1- and 2-D Coordination Networks Based on Porphyrin and Copper: an Example of Supramolecular Isomerism

Bertrand Zimmer,Véronique Bulach,Mir Wais Hosseini,André De Cian,Nathalie Kyritsakas

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY（2002）

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摘要

A high-yield synthesis of atropoisomers of the meso-tetrakis(o-isonicotinoylamidophenyl)porphyrin was achieved. Depending on the crystallising solvent system, the alpha(2)beta2 atropoisomer leads to the formation of either 1-D or 2-D coordination networks in the presence of Cu(OAc)(2).

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关键词

porphyrin,pyridine,isonicotinoyl,coordination network,copper,atropoisomerism

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