Applications of Modulated Temperature Differential Scanning Calorimetry to Polymer Blends and Related Systems
Hot Topics in Thermal Analysis and CalorimetryModulated Temperature Differential Scanning Calorimetry(2006)
摘要
It has been shown in this chapter that the MTDSC technique is a very useful tool in the study of several aspects of polymer
blends and related materials including structured latexes and interpenetrating polymer networks. It is important to note that
the dC
p/dT versus temperature signal may be used not only qualitatively as a sensitive detector of transitions impossible to spot by
other thermal techniques such as conventional DSC and DMTA, but it may also be used to significant advantage in a quantitative
way. It has been shown that it is sensitive to the diffuse interface between phases. Thus, from dC
p/dT versus temperature signals, the weight fraction of the diffuse interface can be quantified. There are many situations where
this will prove to be very valuable.
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