Investigations Into The C-Deuteriation Of Aryl Alkyl Ketones Using Urea As A Pro-Base In The Presence Of A Deuterium Donor

Gregory S. Coumbarides,Jason Eames,Michael J. Suggate,Neluka Weerasooriya

JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS（2006）

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摘要

Results are reported on the regioselective C-deuteriation of a series of enolates derived from the deprotonation of aryl alkyl ketones using dilithiated urea as the pro-base in the presence of a suitable deuterium donor. Copyright (c) 2006 John Wiley & Sons, Ltd.

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alkyl aryl ketones, D-enols, deuterium, enolates and internal deuterium transfer

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