Stereoselective synthesis of the both enantiomers of disparlure, the pheromone of the gypsy moth
TETRAHEDRON(1979)
摘要
The both enantiomers of disparlure [(7 R , 8 S )-(+)-epoxy-2-methyloctadecane and its (7 S ,8 R )-(−)-isomer] were synthesized from (2 R , 3 R )-(+)-tartaric acid in a stereoselective manner. (+)-Disparlure was found to be biologically active.
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