XPS and chiroptical studies on ternary lanthanide complexes of d-camphor-β-sulfonic acid and 1,10-phenanthroline

Dong Hengshan,Ma Hongzhu,Wang Bo,Yang Shiyan

Polyhedron（1997）

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摘要

Nine new chiral complexes of the type Ln(Phen)2L2Cl (Ln = LaIII, PrIII, NdIII, CeIII, SmIII, EuIII, TbIII and HoIII, Phen = 1,10-phenanthroline, L = D-camphor-��-sulfonate ion) have been synthesized and characterized on the basis of elemental analysis, molar conductance, electronic, IR, XPS, circular dichroism (CD) and fluorescence spectra. A seven coordinated model has been proposed for these complexes. Copyright ? 1996 Elsevier Science Ltd.

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关键词

1,10-phenanthroline,Circular dichroism,D-camphor-��-sulfonic acid,Fluorescence spectra,Ternary lanthanide complexes,XP spectra

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