Dynamic thermodynamic resolution of lithiated N-Boc-N′-alkylpiperazines

Steven P. Robinson,Nadeem S. Sheikh,Carl A. Baxter,Iain Coldham

Tetrahedron Letters（2010）

引用 26|浏览26

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摘要

Deprotonation of N-Boc-N′-alkylpiperazines and dynamic thermodynamic resolution (DTR) with a chiral ligand gave, after electrophilic quench, 2-substituted N-Boc-N′-alkylpiperazines with moderate yields and enantioselectivities.

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thermodynamics

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