Tetraethylammonium dichlorotris(2,6-dimethyl-phenylsulfanyl-κS) ruthenium dichloromethane solvate
Acta Crystallographica Section E-structure Reports Online（2006）
摘要
The title mononuclear ruthenium(IV) complex, (C8H 20N)[Ru-(C8H9S)3Cl 2]·CH2Cl2, contains the trigonal {Ru(Sxylyl)3} core (xylyl is 2,6-dimethylphenyl), with S-Ru-S angles in the range 118.07 (6)-123.45 (6)°. The coordination geometry of the central Ru atom is trigonal-bipyramidal, with two Cl atoms in the axial positions. The Ru-S and Ru-Cl bond lengths are 2.1918 (18)-2.2046 (19) and 2.378 (2)-2.385 (2) Å, respectively. © 2006 International Union of Crystallography All rights reserved.
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