Synthese und Struktur gemischt-substituierter Dialane Al2X2{Si(SiMe3)3}2 · 2 THF (X = Cl, Br)

Christoph Klemp,Christoph Üffing, Elke Baum,Hansgeorg Schnöckel

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE（2000）

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摘要

The syntheses of tris(trimethylsilyl)silyl (hypersilyl) and halide substituted dialanes Al2X2{Si(SiMe3)(3)}(2) .. 2THF (X = Cl, Br) are presented. The results of the X-ray diffraction experiments are presented and discussed in comparison to the Al-III compounds AlBr2Si(SiMe3)(3) . THF and AlBr3 . OPh2.

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aluminum,subvalent compounds,crystal structure,metal-metal interactions

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