Electrochemical Rate Constants In Room Temperature Ionic Liquids: The Oxidation Of A Series Of Ferrocene Derivatives
CHEMPHYSCHEM(2006)
摘要
The high-speed channel electrode has been used to measure heterogeneous electron-transfer rates, k0, for a series of ferrocene derivatives in room temperaure ionic liquids (RTILs) under steady-state conditions thus avoiding the problems of ohmic drop and capacitative currents associated with transient methods. The figure shows the three-dimensional surface plot for k0 versus the transfer coefficient, α.
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关键词
electrochemistry, electron transfer, ferrocene derivatives, heterogeneous rate constants, ionic liquids
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