Multigram-Scale Asymmetric Hydrogenation Reactions Using Ru-SYNPHOS^®and Ru-DIFLUORPHOS^®Catalysts

Séverine Jeulin,Nicolas Champion,Philippe Dellis,Virginie Ratovelomanana-Vidal,Jean-Pierre Genêt

SYNTHESIS-STUTTGART（2005）

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摘要

The detailed procedure for the synthesis of Ru-SYNPHOS (R) and Ru-DIFLUORPHOS (R) catalysts are described. These catalysts displayed high rates and are quite effective for the large-scale hydrogenation reactions of unsaturated compounds.

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关键词

ruthenium catalysts,asymmetric catalysis,hydrogenation,ligands,atropisomerism

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Multigram-Scale Asymmetric Hydrogenation Reactions Using Ru-SYNPHOS®and Ru-DIFLUORPHOS®Catalysts

Multigram-Scale Asymmetric Hydrogenation Reactions Using Ru-SYNPHOS^®and Ru-DIFLUORPHOS^®Catalysts