Chemical Synthesis of Deuterium-Labeled and Unlabeled Very Long Chain Polyunsaturated Fatty Acids
TETRAHEDRON LETTERS(2010)
摘要
First syntheses of a deuterium-labeled very long C34-containing polyunsaturated fatty acid, C34:5n5.d(2), and three other unlabeled very long chain C30-32-containing polyunsaturated fatty acids are reported here. These syntheses were achieved by coupling chemically modified C22- and C20-containing polyunsaturated fatty acids with carbanions derived from arylalkyl sulfones, followed by sodium amalgam-mediated desulfonylation.
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关键词
Fatty Acid Metabolism
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