Determination by 1D NOE studies of the stereochemistry of a tricyclic 2-hydroxytetrahydrofuran derivative obtained by hydroformylation of (1R)-(-)-myrtenol

S. Sirol,J.-P. Gorrichon,P. Kalck,P. M. Nieto,G. Commenges

MAGNETIC RESONANCE IN CHEMISTRY（1999）

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摘要

The structure of a new, optically pure 2-hydroxytetrahydrofuran tricyclic compound resulting from the hydroformylation of (1R)-(-)-myrtenol was resolved by one- and two-dimensional H-1 and C-13 NMR. The configurations of the three new asymmetric centres are discussed on the basis of J(H,H) coupling constants, NOE measurements and molecular modelling. Copyright (C) 1999 John Wiley & Sons, Ltd.

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关键词

NMR,H-1 NMR,C-13 NMR,NOESY,myrtenol hydroformylation,tricyclic monoterpene derivative,molecular modelling

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