Rectangular tetranuclear silver(I) and μ8-selenide-centered octanuclear copper(I) complexes containing bis(diphenylphosphino)amide ligands

Qian-Feng Zhang,Zhan Yu,Alexander Rothenberger,Dieter Fenske,Wa-Hung Leung

Inorganica Chimica Acta（2007）

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摘要

Treatment of trinuclear trigonal-bipyramid copper(I) complex [Cu3(μ3-Cl)2(μ-dppa)3][CuCl2] with (Me3Si)2Se in THF gave a novel μ8-selenide-centered octanuclear copper(I) complex [Cu8(μ8-Se)(μ4-Se)(μ4-SeH)3(μ-dppa)4][(Ph2PO)2N]. The reaction undertook a hydrolysis of dppa ligand and a hydrogenation of active Se2− anion.

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关键词

Synthesis,Crystal structure,Copper(I) complex,Silver(I) complex,Bis(diphenylphosphino)amide

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